p-tolyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1->6)-2,3,4-tri-O-benzyl-1-deoxy-1-thio-β-D-glucopyranoside

Base Information

Chemical Name:p-tolyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1->6)-2,3,4-tri-O-benzyl-1-deoxy-1-thio-β-D-glucopyranoside
CAS No.:762287-73-0
Molecular Formula:C₆₈H₇₀O₁₀S
Molecular Weight:1079.36
Hs Code.:

Synonyms:p-tolyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1->6)-2,3,4-tri-O-benzyl-1-deoxy-1-thio-β-D-glucopyranoside

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Chemical Property of p-tolyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1->6)-2,3,4-tri-O-benzyl-1-deoxy-1-thio-β-D-glucopyranoside

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Technology Process of p-tolyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1->6)-2,3,4-tri-O-benzyl-1-deoxy-1-thio-β-D-glucopyranoside

There total 17 articles about p-tolyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1->6)-2,3,4-tri-O-benzyl-1-deoxy-1-thio-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 132201-75-3
2,3,4,6-tetra-O-benzyl-D-glucopyranose trichloroacetimidate

: 479252-05-6
((2R,3R,4S,5R,6S)-3,4,5-Tris-benzyloxy-6-p-tolylsulfanyl-tetrahydro-pyran-2-yl)-methanol

: 1158796-37-2
(2R,3R,4S,5R)-3,4,5-Tris-benzyloxy-2-benzyloxymethyl-6-p-tolylsulfanyl-tetrahydro-pyran

: 762287-73-0
p-tolyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1->6)-2,3,4-tri-O-benzyl-1-deoxy-1-thio-β-D-glucopyranoside

Guidance literature:: With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; acetonitrile; propiononitrile; at -70 ℃; Molecular sieve; Inert atmosphere;
DOI:10.1002/adsc.201000888

Reference yield: 77.0%

: 131531-76-5
p-methylphenyl 2,3,4,6-tetra-O-benzyl-thio-β-D-glucopyranoside

: 479252-05-6
((2R,3R,4S,5R,6S)-3,4,5-Tris-benzyloxy-6-p-tolylsulfanyl-tetrahydro-pyran-2-yl)-methanol

: 762287-73-0
p-tolyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1->6)-2,3,4-tri-O-benzyl-1-deoxy-1-thio-β-D-glucopyranoside

Guidance literature:: p-methylphenyl 2,3,4,6-tetra-O-benzyl-thio-β-D-glucopyranoside; ((2R,3R,4S,5R,6S)-3,4,5-Tris-benzyloxy-6-p-tolylsulfanyl-tetrahydro-pyran-2-yl)-methanol; With N-iodo-succinimide; In dichloromethane; acetonitrile; at -70 ℃; for 0.5h; Molecular sieve; Inert atmosphere;

With trifluorormethanesulfonic acid; In dichloromethane; acetonitrile; at -70 ℃; stereoselective reaction; Molecular sieve; Inert atmosphere;
DOI:10.1002/anie.202013909

Reference yield: 77.0%

: 2,3,4,6-tetra-O-benzyl-D-glucopyranosyl diphenyl phosphate

: 479252-05-6
((2R,3R,4S,5R,6S)-3,4,5-Tris-benzyloxy-6-p-tolylsulfanyl-tetrahydro-pyran-2-yl)-methanol

: 1158796-37-2
(2R,3R,4S,5R)-3,4,5-Tris-benzyloxy-2-benzyloxymethyl-6-p-tolylsulfanyl-tetrahydro-pyran

: 762287-73-0
p-tolyl 2,3,4,6-tetra-O-benzyl-β-D-glucopyranosyl-(1->6)-2,3,4-tri-O-benzyl-1-deoxy-1-thio-β-D-glucopyranoside

Guidance literature:: With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; acetonitrile; propiononitrile; at -70 ℃; Molecular sieve; Inert atmosphere;
DOI:10.1002/adsc.201000888