Technology Process of C16H24O3S2
There total 3 articles about C16H24O3S2 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
C15H20O3S2;
With
magnesium bromide ethyl etherate;
In
dichloromethane;
at -78 ℃;
for 1h;
methylmagnesium bromide;
In
diethyl ether; dichloromethane;
at -78 ℃;
for 1.5h;
stereoselective reaction;
DOI:10.1016/j.tet.2013.02.008
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: diisobutylaluminium hydride / dichloromethane; toluene / 2 h / -78 °C
1.2: 2.5 h / 0 - 20 °C
2.1: magnesium bromide ethyl etherate / dichloromethane / 1 h / -78 °C
2.2: 1.5 h / -78 °C
With
diisobutylaluminium hydride; magnesium bromide ethyl etherate;
In
dichloromethane; toluene;
2.2: |Grignard Reaction;
DOI:10.1016/j.tet.2013.02.008
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: (±)-CSA / N,N-dimethyl-formamide / 1.5 h / 20 °C
2.1: diisobutylaluminium hydride / dichloromethane; toluene / 2 h / -78 °C
2.2: 2.5 h / 0 - 20 °C
3.1: magnesium bromide ethyl etherate / dichloromethane / 1 h / -78 °C
3.2: 1.5 h / -78 °C
With
diisobutylaluminium hydride; magnesium bromide ethyl etherate;
In
dichloromethane; N,N-dimethyl-formamide; toluene;
3.2: |Grignard Reaction;
DOI:10.1016/j.tet.2013.02.008