tert-butyl(((3E,5E)-6-(dimethyl(phenyl)silyl)hexa-3,5-dien-1-yl)oxy)dimethylsilane

Base Information

Chemical Name:tert-butyl(((3E,5E)-6-(dimethyl(phenyl)silyl)hexa-3,5-dien-1-yl)oxy)dimethylsilane
CAS No.:1613161-87-7
Molecular Formula:C₂₀H₃₄OSi₂
Molecular Weight:346.66
Hs Code.:

Synonyms:tert-butyl(((3E,5E)-6-(dimethyl(phenyl)silyl)hexa-3,5-dien-1-yl)oxy)dimethylsilane

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Chemical Property of tert-butyl(((3E,5E)-6-(dimethyl(phenyl)silyl)hexa-3,5-dien-1-yl)oxy)dimethylsilane

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Technology Process of tert-butyl(((3E,5E)-6-(dimethyl(phenyl)silyl)hexa-3,5-dien-1-yl)oxy)dimethylsilane

There total 4 articles about tert-butyl(((3E,5E)-6-(dimethyl(phenyl)silyl)hexa-3,5-dien-1-yl)oxy)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 1613161-89-9
(3E,5E)-6-(dimethyl(phenyl)silyl)hexa-3,5-dien-1-ol

: 18162-48-6
tert-butyldimethylsilyl chloride

: 1613161-87-7
tert-butyl(((3E,5E)-6-(dimethyl(phenyl)silyl)hexa-3,5-dien-1-yl)oxy)dimethylsilane

Guidance literature:: With dmap; triethylamine; In dichloromethane; at 20 ℃; for 12h; Inert atmosphere;
DOI:10.1021/ol501329t

Reference yield:

: 591235-22-2
6-(trimethylsilyl)hexa-3,5-diyn-1-ol

: 1613161-87-7
tert-butyl(((3E,5E)-6-(dimethyl(phenyl)silyl)hexa-3,5-dien-1-yl)oxy)dimethylsilane

Guidance literature:: Multi-step reaction with 4 steps

1: lithium aluminium tetrahydride / diethyl ether / 3 h / 0 - 20 °C / Inert atmosphere

2: potassium carbonate / methanol / 1 h / 20 °C / Inert atmosphere

3: [Pt(DVDS)]-P^tBu / tetrahydrofuran / 20 °C / Inert atmosphere

4: triethylamine; dmap / dichloromethane / 12 h / 20 °C / Inert atmosphere

With dmap; lithium aluminium tetrahydride; potassium carbonate; triethylamine; In tetrahydrofuran; methanol; diethyl ether; dichloromethane;
DOI:10.1021/ol501329t

Reference yield:

: 377774-73-7
(E)-6-Trimethylsilanyl-hex-3-en-5-yn-1-ol

: 1613161-87-7
tert-butyl(((3E,5E)-6-(dimethyl(phenyl)silyl)hexa-3,5-dien-1-yl)oxy)dimethylsilane

Guidance literature:: Multi-step reaction with 3 steps

1: potassium carbonate / methanol / 1 h / 20 °C / Inert atmosphere

2: [Pt(DVDS)]-P^tBu / tetrahydrofuran / 20 °C / Inert atmosphere

3: triethylamine; dmap / dichloromethane / 12 h / 20 °C / Inert atmosphere

With dmap; potassium carbonate; triethylamine; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1021/ol501329t