dibutyl (2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)phosphate

Base Information

• Chemical Name: dibutyl (2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)phosphate
• CAS No.: 1426843-81-3
• Molecular Formula: C₃₄H₃₉O₁₁P
• Molecular Weight: 654.651
• Mol file: 1426843-81-3.mol

Synonyms:dibutyl (2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)phosphate

Chemical Property of dibutyl (2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)phosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of dibutyl (2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)phosphate

There total 3 articles about dibutyl (2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)phosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

dibutyl phosphate (107-66-4) + 2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl bromide (4348-68-9) → dibutyl (2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)phosphate (1426843-81-3)

Guidance literature:

With N-ethyl-N,N-diisopropylamine; In acetonitrile; at 20 ℃; for 2h; stereoselective reaction;

DOI:10.1007/s11172-016-1654-y

Reference yield: 73.0%

dibutyl phosphate (107-66-4) → dibutyl (2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)phosphate (1426843-81-3)

Guidance literature:

In dichloromethane; at 0 - 20 ℃; for 2h;

Reference yield:

dibutyl phosphate (107-66-4) + 2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl bromide (4348-68-9) → dibutyl (2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl)phosphate (1426843-81-3) + dibutyl (2,3,5-tri-O-benzoyl-β-D-arabinofuranosyl)phosphate

Guidance literature:

With N-ethyl-N,N-diisopropylamine; In acetonitrile; at 20 ℃; for 2h; Concentration; Overall yield = 85 %;

DOI:10.1007/s11172-016-1654-y

upstream raw materials:

dibutyl phosphate

2,3,5-tri-O-benzoyl-α-D-arabinofuranosyl bromide

Downstream raw materials:

11-(2,3,5-tri-O-benzoyl α-D-arabinofuranosyl-(1→5)-β-D-arabinofuranosyl)undecene