4-methylthio-1,2-diphenyl-4-(N-allyl-N-phenyl)amino-1,3-diaza-1,3-butadiene

Base Information

• Chemical Name: 4-methylthio-1,2-diphenyl-4-(N-allyl-N-phenyl)amino-1,3-diaza-1,3-butadiene
• CAS No.: 459175-48-5
• Molecular Formula: C₂₄H₂₃N₃S
• Molecular Weight: 385.533
• Mol file: 459175-48-5.mol

Synonyms:4-methylthio-1,2-diphenyl-4-(N-allyl-N-phenyl)amino-1,3-diaza-1,3-butadiene

Chemical Property of 4-methylthio-1,2-diphenyl-4-(N-allyl-N-phenyl)amino-1,3-diaza-1,3-butadiene

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

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Technology Process of 4-methylthio-1,2-diphenyl-4-(N-allyl-N-phenyl)amino-1,3-diaza-1,3-butadiene

There total 1 articles about 4-methylthio-1,2-diphenyl-4-(N-allyl-N-phenyl)amino-1,3-diaza-1,3-butadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

allyl bromide (106-95-6) + 2-Methyl-1-phenyl-3-{phenyl-[(E)-phenylimino]-methyl}-isothiourea → 4-methylthio-1,2-diphenyl-4-(N-allyl-N-phenyl)amino-1,3-diaza-1,3-butadiene (459175-48-5)

Guidance literature:

With potassium carbonate; Yield given. Multistep reaction; 1.) Me₂CO, reflux, 2 h, 2.) room temperature, 7-9 h;

DOI:10.1016/S0040-4020(97)00873-9

Reference yield: 91.0%

3,3-Dimethylacryloyl chloride (3350-78-5) + 4-methylthio-1,2-diphenyl-4-(N-allyl-N-phenyl)amino-1,3-diaza-1,3-butadiene (459175-48-5) → 6-(Allyl-phenyl-amino)-5-isopropenyl-2,3-diphenyl-3H-pyrimidin-4-one (198702-05-5)

Guidance literature:

With triethylamine; In dichloromethane; for 2h; Product distribution; Ambient temperature; generation of ketene; <4+2> cycloaddition reactions of 4-(N-allyl-N-aryl)amino-1,3-diaza-1,3-butadienes with vinyl-, isopropenyl- and chloroketenes;

DOI:10.1016/S0040-4020(97)00873-9

Reference yield: 89.0%

chloroacetyl chloride (79-04-9) + 4-methylthio-1,2-diphenyl-4-(N-allyl-N-phenyl)amino-1,3-diaza-1,3-butadiene (459175-48-5) → 6-(Allyl-phenyl-amino)-5-methylsulfanyl-2,3-diphenyl-3H-pyrimidin-4-one

Guidance literature:

With triethylamine; In dichloromethane; for 2h; Ambient temperature;

DOI:10.1016/S0040-4020(97)00873-9

upstream raw materials:

allyl bromide

Downstream raw materials:

6-(Allyl-phenyl-amino)-5-isopropenyl-2,3-diphenyl-3H-pyrimidin-4-one