C₄₈H₅₀F₃N₃O₁₁SSi

Base Information Edit

Chemical Name:C₄₈H₅₀F₃N₃O₁₁SSi
CAS No.:182201-67-8
Molecular Formula:C₄₈H₅₀F₃N₃O₁₁SSi
Molecular Weight:962.085
Hs Code.:
Mol file:182201-67-8.mol

C<sub>48</sub>H<sub>50</sub>F<sub>3</sub>N<sub>3</sub>O<sub>11</sub>SSi

Synonyms:C₄₈H₅₀F₃N₃O₁₁SSi

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Chemical Property of C₄₈H₅₀F₃N₃O₁₁SSi Edit

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Technology Process of C₄₈H₅₀F₃N₃O₁₁SSi

There total 25 articles about C₄₈H₅₀F₃N₃O₁₁SSi which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 58479-61-1
tert-butylchlorodiphenylsilane

: 182201-66-7
C₃₂H₃₂F₃N₃O₁₁S

: 182201-67-8
C₄₈H₅₀F₃N₃O₁₁SSi

Guidance literature:: With dmap; In dichloromethane; at 23 ℃; for 13h;
DOI:10.1021/ja962480t

Reference yield:

: 111726-43-3
3,4-(methylenedioxy)phenyl methoxymethyl ether

: 182201-67-8
C₄₈H₅₀F₃N₃O₁₁SSi

Guidance literature:: Multi-step reaction with 19 steps

1: 1.) BuLi, tetramethylethylene diamine / 1.) hexane, 0 deg C, 4 h, 2.) hexane, from -78 deg C to 23 deg C, 15 min

2: 1.) BuLi / 1.) THF, -30 deg C, 13 h

3: CH₃SO₃H / CH₂Cl₂ / 0 °C

4: 1.) NaH / 1.) DMF, 0 deg C, 5 min, 2.) DMF, 23 deg C, 40 min

5: 99 percent / piperidine, acetic acid / benzene / 18 h / 23 °C

6: 94 percent / Et₃N, HCOOH, Pd(PPh₃)4 / 4 h / 23 °C

7: (PhO)2P(O)N₃, Et₃N, 4 Angstroem molecular sieves / toluene / 2 h / 70 °C

8: 1 h / 23 °C

9: 97 percent / H₂, Rh<(COD)-(R,R)-DIPAMP>(+)*BF₄(-) / 16 h / 23 °C / 2280 Torr

10: BF₃*Et₂O, H₂O / CH₂Cl₂ / 0.17 h / 0 °C

11: BF₃*Et₂O, 4 Angstroem molecular sieves / CH₂Cl₂ / 18 h / 23 °C

12: 100 percent / H₂ / 10percent Pd/C / ethyl acetate / 6 h / 23 °C / 760 Torr

13: 61 percent / HOAc / 18 h / 23 °C

14: 87 percent / Cs₂CO₃ / dimethylformamide / 1 h / 23 °C

15: diisobutylaluminum hydride / toluene / 5 h / -78 °C

16: KF*2H₂O / methanol / 0.33 h / 23 °C

17: CH₃SO₃H, 3 Angstroem molecular sieves / CH₂Cl₂ / 5 h / 23 °C

18: 72 percent / Et₃N, DMAP / CH₂Cl₂ / 6 h / 23 °C

19: 89 percent / DMAP / CH₂Cl₂ / 13 h / 23 °C

With piperidine; dmap; potassium fluoride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; formic acid; methanesulfonic acid; N,N,N,N,-tetramethylethylenediamine; Rh<(COD)-(R,R)-DIPAMP>(+)*BF4(-); 3 A molecular sieve; 4 A molecular sieve; diphenyl phosphoryl azide; boron trifluoride diethyl etherate; water; hydrogen; sodium hydride; diisobutylaluminium hydride; caesium carbonate; acetic acid; triethylamine; palladium on activated charcoal; In methanol; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; toluene; benzene;
DOI:10.1021/ja962480t

Reference yield:

: 187040-02-4
5-methoxy methoxy-4-methyl benzo[d][1,3]dioxole

: 182201-67-8
C₄₈H₅₀F₃N₃O₁₁SSi

Guidance literature:: Multi-step reaction with 18 steps

1: 1.) BuLi / 1.) THF, -30 deg C, 13 h

2: CH₃SO₃H / CH₂Cl₂ / 0 °C

3: 1.) NaH / 1.) DMF, 0 deg C, 5 min, 2.) DMF, 23 deg C, 40 min

4: 99 percent / piperidine, acetic acid / benzene / 18 h / 23 °C

5: 94 percent / Et₃N, HCOOH, Pd(PPh₃)4 / 4 h / 23 °C

6: (PhO)2P(O)N₃, Et₃N, 4 Angstroem molecular sieves / toluene / 2 h / 70 °C

7: 1 h / 23 °C

8: 97 percent / H₂, Rh<(COD)-(R,R)-DIPAMP>(+)*BF₄(-) / 16 h / 23 °C / 2280 Torr

9: BF₃*Et₂O, H₂O / CH₂Cl₂ / 0.17 h / 0 °C

10: BF₃*Et₂O, 4 Angstroem molecular sieves / CH₂Cl₂ / 18 h / 23 °C

11: 100 percent / H₂ / 10percent Pd/C / ethyl acetate / 6 h / 23 °C / 760 Torr

12: 61 percent / HOAc / 18 h / 23 °C

13: 87 percent / Cs₂CO₃ / dimethylformamide / 1 h / 23 °C

14: diisobutylaluminum hydride / toluene / 5 h / -78 °C

15: KF*2H₂O / methanol / 0.33 h / 23 °C

16: CH₃SO₃H, 3 Angstroem molecular sieves / CH₂Cl₂ / 5 h / 23 °C

17: 72 percent / Et₃N, DMAP / CH₂Cl₂ / 6 h / 23 °C

18: 89 percent / DMAP / CH₂Cl₂ / 13 h / 23 °C

With piperidine; dmap; potassium fluoride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; formic acid; methanesulfonic acid; Rh<(COD)-(R,R)-DIPAMP>(+)*BF4(-); 3 A molecular sieve; 4 A molecular sieve; diphenyl phosphoryl azide; boron trifluoride diethyl etherate; water; hydrogen; sodium hydride; diisobutylaluminium hydride; caesium carbonate; acetic acid; triethylamine; palladium on activated charcoal; In methanol; dichloromethane; ethyl acetate; N,N-dimethyl-formamide; toluene; benzene;
DOI:10.1021/ja962480t