(4S,6R)-7-(tert-butyldiphenylsilyloxy)-6-methylhept-1-en-4-yl 3-(4-methoxybenzyloxy) propanoate

Base Information

Chemical Name:(4S,6R)-7-(tert-butyldiphenylsilyloxy)-6-methylhept-1-en-4-yl 3-(4-methoxybenzyloxy) propanoate
CAS No.:1598413-56-9
Molecular Formula:C₃₅H₄₆O₅Si
Molecular Weight:574.833
Hs Code.:

Synonyms:(4S,6R)-7-(tert-butyldiphenylsilyloxy)-6-methylhept-1-en-4-yl 3-(4-methoxybenzyloxy) propanoate

Suppliers and Price of (4S,6R)-7-(tert-butyldiphenylsilyloxy)-6-methylhept-1-en-4-yl 3-(4-methoxybenzyloxy) propanoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (4S,6R)-7-(tert-butyldiphenylsilyloxy)-6-methylhept-1-en-4-yl 3-(4-methoxybenzyloxy) propanoate

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of (4S,6R)-7-(tert-butyldiphenylsilyloxy)-6-methylhept-1-en-4-yl 3-(4-methoxybenzyloxy) propanoate

There total 3 articles about (4S,6R)-7-(tert-butyldiphenylsilyloxy)-6-methylhept-1-en-4-yl 3-(4-methoxybenzyloxy) propanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 1598413-55-8
(4S,6R)-7-(tert-butyldiphenylsilyloxy)-6-methylhept-1-en-4-ol

: 392333-41-4
3-(4-methoxybenzyloxy)propanoic acid

: 1598413-56-9
(4S,6R)-7-(tert-butyldiphenylsilyloxy)-6-methylhept-1-en-4-yl 3-(4-methoxybenzyloxy) propanoate

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In dichloromethane; at 0 - 20 ℃; for 12h; Inert atmosphere;
DOI:10.1021/ol500875e

Reference yield:

: 186641-79-2
(R)-4-((tert-Butyldiphenylsilyl)oxy)-3-methylbutanal

: 1598413-56-9
(4S,6R)-7-(tert-butyldiphenylsilyloxy)-6-methylhept-1-en-4-yl 3-(4-methoxybenzyloxy) propanoate

Guidance literature:: Multi-step reaction with 2 steps

1.1: C₂₅H₄₅BO / diethyl ether / 1 h / -78 - 20 °C / Inert atmosphere

1.2: 8 h / -78 °C / Inert atmosphere

2.1: dmap; dicyclohexyl-carbodiimide / dichloromethane / 12 h / 0 - 20 °C / Inert atmosphere

With dmap; C₂₅H₄₅BO; dicyclohexyl-carbodiimide; In diethyl ether; dichloromethane;
DOI:10.1021/ol500875e

Reference yield:

: 144693-95-8
(4R)-5-(tert-butyldiphenylsilyloxy)-4-methyl-1-pentene

: 1598413-56-9
(4S,6R)-7-(tert-butyldiphenylsilyloxy)-6-methylhept-1-en-4-yl 3-(4-methoxybenzyloxy) propanoate

Guidance literature:: Multi-step reaction with 3 steps

1.1: ozone / dichloromethane / 3 h / -78 °C / Inert atmosphere

1.2: -78 - 20 °C / Inert atmosphere

2.1: C₂₅H₄₅BO / diethyl ether / 1 h / -78 - 20 °C / Inert atmosphere

2.2: 8 h / -78 °C / Inert atmosphere

3.1: dmap; dicyclohexyl-carbodiimide / dichloromethane / 12 h / 0 - 20 °C / Inert atmosphere

With dmap; C₂₅H₄₅BO; ozone; dicyclohexyl-carbodiimide; In diethyl ether; dichloromethane;
DOI:10.1021/ol500875e