(1R,2R,6S)-6-(3-bromoprop-1-en-2-yl)-3-methylcyclohex-3-ene-1,2-diol

Base Information

• Chemical Name: (1R,2R,6S)-6-(3-bromoprop-1-en-2-yl)-3-methylcyclohex-3-ene-1,2-diol
• CAS No.: 1424336-02-6
• Molecular Formula: C₁₀H₁₅BrO₂
• Molecular Weight: 247.132
• Mol file: 1424336-02-6.mol

Synonyms:(1R,2R,6S)-6-(3-bromoprop-1-en-2-yl)-3-methylcyclohex-3-ene-1,2-diol

Chemical Property of (1R,2R,6S)-6-(3-bromoprop-1-en-2-yl)-3-methylcyclohex-3-ene-1,2-diol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1R,2R,6S)-6-(3-bromoprop-1-en-2-yl)-3-methylcyclohex-3-ene-1,2-diol

There total 1 articles about (1R,2R,6S)-6-(3-bromoprop-1-en-2-yl)-3-methylcyclohex-3-ene-1,2-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 34.0%

(1R,2R,6S)-3-methyl-6-(1-methylethenyl)cyclohex-3-ene-1,2-diol (935670-67-0) → (1R,2R,6S)-6-(3-bromoprop-1-en-2-yl)-3-methylcyclohex-3-ene-1,2-diol (1424336-02-6)

Guidance literature:

With N-Bromosuccinimide; di-tert-butyl peroxide; In tetrachloromethane; for 2h; Reflux;

DOI:10.1016/j.bmc.2013.01.003

Reference yield: 72.0%

(1R,2R,6S)-6-(3-bromoprop-1-en-2-yl)-3-methylcyclohex-3-ene-1,2-diol (1424336-02-6) + sodium acetate (127-09-3) → 2-((1S,5R,6R)-5,6-dihydroxy-4-methylcyclohex-3-enyl)allyl acetate (1424336-03-7)

Guidance literature:

In dimethyl sulfoxide; at 20 ℃; for 24h;

DOI:10.1016/j.bmc.2013.01.003

Reference yield: 63.0%

morpholine (110-91-8,99108-56-2) + (1R,2R,6S)-6-(3-bromoprop-1-en-2-yl)-3-methylcyclohex-3-ene-1,2-diol (1424336-02-6) → C14H23NO3 (1424336-07-1)

Guidance literature:

morpholine; (1R,2R,6S)-6-(3-bromoprop-1-en-2-yl)-3-methylcyclohex-3-ene-1,2-diol; In chloroform; at 20 ℃; for 48h;

With sodium hydrogencarbonate; In chloroform; water;

DOI:10.1016/j.bmc.2013.01.003

upstream raw materials:

(1R,2R,6S)-3-methyl-6-(1-methylethenyl)cyclohex-3-ene-1,2-diol

Downstream raw materials:

C₁₀H₁₆O₃

C₁₄H₂₃NO₃

C₁₄H₂₆N₂O₂

(1R,2R,6S)-3-methyl-6-(3-(propylthio)prop-1-en-2-yl)cyclohex-3-ene-1,2-diol