di-μ-phenylhydrazido(2-)-bis[chloro(η-cyclopentadienyl)titanium]

Base Information

• Chemical Name: di-μ-phenylhydrazido(2-)-bis[chloro(η-cyclopentadienyl)titanium]
• CAS No.: 103432-49-1
• Molecular Formula: C₂₂H₂₂Cl₂N₄Ti₂
• Molecular Weight: 509.109
• Mol file: 103432-49-1.mol

Synonyms:di-μ-phenylhydrazido(2-)-bis[chloro(η-cyclopentadienyl)titanium]

Chemical Property of di-μ-phenylhydrazido(2-)-bis[chloro(η-cyclopentadienyl)titanium]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of di-μ-phenylhydrazido(2-)-bis[chloro(η-cyclopentadienyl)titanium]

There total 1 articles about di-μ-phenylhydrazido(2-)-bis[chloro(η-cyclopentadienyl)titanium] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

dichloro(η-cyclopentadienyl)(N(1)-phenylhydrazido(1-)-N(1),N(2))titanium(IV) (89340-92-1) → di-μ-phenylhydrazido(2-)-bis[chloro(η-cyclopentadienyl)titanium] (103432-49-1)

Guidance literature:

With NH₂C(CH₃)3; In dichloromethane; byproducts: (NH3C(CH3)3)Cl; NH2-t-Bu added to a soln. of Ti-complex; stirred for 48 h at 20°C; filtered; evapd.; washed with hexane; dried in vacuo; elem. anal.;

DOI:10.1039/DT9860000393

Reference yield: 80.0%

di-μ-phenylhydrazido(2-)-bis[chloro(η-cyclopentadienyl)titanium] (103432-49-1) → chloro(η-cyclopentadienyl)iodo(phenylhydrazido(1-))titanium(IV) (103432-35-5)

Guidance literature:

With HI; In toluene; a soln. of Ti-complex allowed to react with a soln. of HI; elem. anal.;

DOI:10.1039/DT9860000393

Reference yield:

di-μ-phenylhydrazido(2-)-bis[chloro(η-cyclopentadienyl)titanium] (103432-49-1) → dichloro(η-cyclopentadienyl)(N(1)-phenylhydrazido(1-)-N(1),N(2))titanium(IV) (89340-92-1)

Guidance literature:

With HCl; In toluene; a soln. of Ti-complex allowed to react with a soln. of HCl;

DOI:10.1039/DT9860000393

upstream raw materials:

dichloro(η-cyclopentadienyl)(N(1)-phenylhydrazido(1-)-N(1),N(2))titanium(IV)

Downstream raw materials:

dichloro(η-cyclopentadienyl)(N(1)-phenylhydrazido(1-)-N(1),N(2))titanium(IV)

chloro(η-cyclopentadienyl)iodo(phenylhydrazido(1-))titanium(IV)