Methyl (E)-4-<2-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthalenyl)ethenyl>benzoate

Base Information

Chemical Name:Methyl (E)-4-<2-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthalenyl)ethenyl>benzoate
CAS No.:102121-54-0
Molecular Formula:C₂₄H₂₈O₂
Molecular Weight:348.485
Hs Code.:

Synonyms:Methyl (E)-4-<2-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthalenyl)ethenyl>benzoate

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Chemical Property of Methyl (E)-4-<2-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthalenyl)ethenyl>benzoate

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Technology Process of Methyl (E)-4-<2-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthalenyl)ethenyl>benzoate

There total 5 articles about Methyl (E)-4-<2-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthalenyl)ethenyl>benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 24.0%

: 1571-08-0
methyl 4-formylbenzoate

: 119436-53-2
methyl 4-((Z)-2-(1,2,3,4-tetrahydro-1,1,4,4-tetramethylnaphthalen-6-yl)vinyl)benzoate

: 102121-54-0
Methyl (E)-4-<2-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthalenyl)ethenyl>benzoate

Guidance literature:: (5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthalenyl)methyl-triphenyl-phosphonium bromide; With sodium hydride; In dimethyl sulfoxide; at 20 ℃; for 0.5h;

methyl 4-formylbenzoate; In dimethyl sulfoxide; at 20 ℃; for 5h;

Reference yield:

: 1571-08-0
methyl 4-formylbenzoate

: C₁₈H₁₅BrPCH₂C₁₄H₁₉

: 119436-53-2
methyl 4-((Z)-2-(1,2,3,4-tetrahydro-1,1,4,4-tetramethylnaphthalen-6-yl)vinyl)benzoate

: 102121-54-0
Methyl (E)-4-<2-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthalenyl)ethenyl>benzoate

Guidance literature:: With 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine; In tetrahydrofuran; at 0 ℃; for 6h; Title compound not separated from byproducts.;
DOI:10.1021/ol0001665

Reference yield:

: 6683-48-3
1,1,4,4,6-pentamethyl-1,2,3,4-tetrahydronaphthalene

: 102121-54-0
Methyl (E)-4-<2-(5,6,7,8-tetrahydro-5,5,8,8-tetramethyl-2-naphthalenyl)ethenyl>benzoate

Guidance literature:: Multi-step reaction with 3 steps

1: N-bromosuccinimide, azobisisobutyronitrile / CHCl₃

2: benzene / 5 h / Heating

3: NaOMe / methanol

With N-Bromosuccinimide; 2,2'-azobis(isobutyronitrile); sodium methylate; In methanol; chloroform; benzene;
DOI:10.1021/jm00125a027