[(C₅(CH₃)5)Re(NO)(P(C₆H₄C(CH₃)3)3)(CH₃)]

Base Information

• Chemical Name: [(C₅(CH₃)5)Re(NO)(P(C₆H₄C(CH₃)3)3)(CH₃)]
• CAS No.: 329984-47-6
• Molecular Formula: C₄₁H₅₇NOPRe
• Molecular Weight: 797.09

Synonyms:[(C₅(CH₃)5)Re(NO)(P(C₆H₄C(CH₃)3)3)(CH₃)]

Chemical Property of [(C₅(CH₃)5)Re(NO)(P(C₆H₄C(CH₃)3)3)(CH₃)]

Chemical Property:

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Technology Process of [(C₅(CH₃)5)Re(NO)(P(C₆H₄C(CH₃)3)3)(CH₃)]

There total 1 articles about [(C₅(CH₃)5)Re(NO)(P(C₆H₄C(CH₃)3)3)(CH₃)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

[(C5(CH3)5)Re(NO)(P(C6H4C(CH3)3)3)(CO)](1+)*BF4(1-)=[(C5(CH3)5)Re(NO)(P(C6H4C(CH3)3)3)(CO)]BF4 (329984-39-6) + borane tetrahydrofuran + lithium triethylborohydride (22560-16-3) → [(C5(CH3)5)Re(NO)(P(C6H4C(CH3)3)3)(CH3)] (329984-47-6)

Guidance literature:

In tetrahydrofuran; soln. of LiEt3BH in THF added to stirred suspn. of Re complex in THF in Schlenk flask; after 10 min BH3*THF added; after 0.5 h solvent removed in vac.; extd. (benzene); passed through column of SiO2; solvent removed by rotary evapn. and oil pump vac.; elem. anal.;

DOI:10.1016/S0022-328X(00)00528-3

Reference yield: 88.0%

tetrafluoroboric acid diethyl ether (67969-82-8) + [(C5(CH3)5)Re(NO)(P(C6H4C(CH3)3)3)(CH3)] (329984-47-6) + trimethylsilyl-1,3-butadiyne (4526-06-1) → C5(CH3)5Re(NO)(HC4Si(CH3)3)P(C6H4C4H9)3(1+)*BF4(1-)*0.5CH2Cl2=C5(CH3)5Re(NO)(HC4Si(CH3)3)P(C6H4C4H9)3BF4*0.5CH2Cl2

Guidance literature:

With dichloromethane; In chlorobenzene; HBF4*Et2O was added with stirring to a soln. of complex in chlorobenzeneat -45°C, after 10 min diyne was added, the bath was warmed to r oom temp., 24 h; the solvent was removed, CH2cl2 was added, hexane was added, ppt. was filtered and air-dried; elem. anal.;

DOI:10.1021/om000961m

Reference yield: 80.0%

tetrafluoroboric acid diethyl ether (67969-82-8) + [(C5(CH3)5)Re(NO)(P(C6H4C(CH3)3)3)(CH3)] (329984-47-6) + acetylene (74-86-2,25067-58-7) → C5(CH3)5Re(NO)(HCCH)P(C6H4C4H9)3(1+)*BF4(1-)=C5(CH3)5Re(NO)(HCCH)P(C6H4C4H9)3BF4

Guidance literature:

In chlorobenzene; to a soln. of complex in chlorobenzene at -45°C was added HBF4*ET2O with stirring, after 10 min acetylene was bubbled through the mixt. for 10 min, then was heated to 80°C for 30 min; the solvent was removed, the residue was dissolved in a min of CH2Cl2, filtered into a stirred Et2O, ppt. was filtered, washed with Et2O and air-dried; elem. anal.;

DOI:10.1021/om000961m

upstream raw materials:

[(C₅(CH₃)5)Re(NO)(P(C₆H₄C(CH₃)3)3)(CO)]⁽¹⁺⁾*BF₄^(1-)=[(C₅(CH₃)5)Re(NO)(P(C₆H₄C(CH₃)3)3)(CO)]BF₄

lithium triethylborohydride

Downstream raw materials:

[(C₅(CH₃)5)Re(NO)(P(C₆H₄C(CH₃)3)3)(CH₃)]⁽¹⁺⁾*PF₆^(1-)=[(C₅(CH₃)5)Re(NO)(P(C₆H₄C(CH₃)3)3)(CH₃)]PF₆

[(C₅(CH₃)5)Re(NO)(P(C₆H₄C(CH₃)3)3)(CH₃)]⁽¹⁺⁾*SbF₆^(1-)=[(C₅(CH₃)5)Re(NO)(P(C₆H₄C(CH₃)3)3)(CH₃)]SbF₆

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