Bromozinc(1+);1-chlorobutane

Base Information

• Chemical Name: Bromozinc(1+);1-chlorobutane
• CAS No.: 155589-48-3
• Molecular Formula: C₄H₈BrClZn
• Molecular Weight: 236.855
• DSSTox Substance ID: DTXSID80400307
• Mol file: 155589-48-3.mol

Synonyms:bromozinc(1+);1-chlorobutane;155589-48-3;4-CHLOROBUTYLZINC BROMIDE;DTXSID80400307;J-009208

Chemical Property of Bromozinc(1+);1-chlorobutane

Chemical Property:

• Vapor Pressure: 103mmHg at 25°C
• Boiling Point: °Cat760mmHg
• Flash Point: 1℉
• PSA: 0.00000
• Density: 0.98g/mLat25℃
• LogP: 2.81610
• Storage Temp.: 2-8°C
• Sensitive.: Air Sensitive
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 2
• Exact Mass: 233.87893
• Heavy Atom Count: 7
• Complexity: 15.1

Purity/Quality:

98% ^*data from raw suppliers

4-Chlorobutylzinc bromide solution 0.5M in THF ^*data from reagent suppliers

Safty Information:

• Hazard Codes: F,Xn
• Statements: 14-19-22-36/38-40-36/37
• Safety Statements: 16-26-33-36-36/37

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: [CH2-]CCCCl.[Zn+]Br

Technology Process of Bromozinc(1+);1-chlorobutane

There total 1 articles about Bromozinc(1+);1-chlorobutane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

4-chlorobutyl bromide (6940-78-9) + zinc (7440-66-6) → 4‐chlorobutylzinc bromide (155589-48-3)

Guidance literature:

With iodine; In N,N-dimethyl acetamide; at 80 ℃; Schlenk technique; Inert atmosphere; Sealed tube;

DOI:10.1021/acs.joc.8b02201

upstream raw materials:

4-chlorobutyl bromide

zinc

Refernces

• 1、 Fulton, Tyler J.,Alley, Phebe L.,Rensch, Heather R.,Ackerman, Adriana M.,Berlin, Cameron B.,Krout, Michael R.. "Access to Functionalized Quaternary Stereocenters via the Copper-Catalyzed Conjugate Addition of Monoorganozinc Bromide Reagents Enabled by N, N-Dimethylacetamide". . p. 14723 - 14732. Retrieved 2018/11/23.