3-(tert-butyl-dimethyl-silanyloxymethyl)-2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-pent-4-enoic acid diethylamide

Base Information

Chemical Name:3-(tert-butyl-dimethyl-silanyloxymethyl)-2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-pent-4-enoic acid diethylamide
CAS No.:339046-87-6
Molecular Formula:C₃₄H₅₅NO₃Si₂
Molecular Weight:581.987
Hs Code.:

3-(<i>tert</i>-butyl-dimethyl-silanyloxymethyl)-2-[2-(<i>tert</i>-butyl-diphenyl-silanyloxy)-ethyl]-pent-4-enoic acid diethylamide

Synonyms:3-(tert-butyl-dimethyl-silanyloxymethyl)-2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-pent-4-enoic acid diethylamide

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Chemical Property of 3-(tert-butyl-dimethyl-silanyloxymethyl)-2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-pent-4-enoic acid diethylamide

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Technology Process of 3-(tert-butyl-dimethyl-silanyloxymethyl)-2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-pent-4-enoic acid diethylamide

There total 3 articles about 3-(tert-butyl-dimethyl-silanyloxymethyl)-2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-pent-4-enoic acid diethylamide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 339046-87-6
3-(tert-butyl-dimethyl-silanyloxymethyl)-2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-pent-4-enoic acid diethylamide

Guidance literature:: Multi-step reaction with 2 steps

1.1: 97 percent / imidazole; DMAP / CH₂Cl₂ / 18 h

2.1: diisopropylamine; n-butyllithium / hexane; tetrahydrofuran / 1 h / -78 °C

2.2: 79 percent / tetrahydrofuran; hexane / 5 h / -78 - 20 °C

With 1H-imidazole; dmap; n-butyllithium; diisopropylamine; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1021/ja004325r

Reference yield:

: 107080-45-5
(S)-(+)-β-vinyl-γ-butyrolactone

: 339046-87-6
3-(tert-butyl-dimethyl-silanyloxymethyl)-2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-pent-4-enoic acid diethylamide

Guidance literature:: Multi-step reaction with 3 steps

1.1: 82 percent / AlMe₃ / hexane; CH₂Cl₂ / 0 - 20 °C

2.1: 97 percent / imidazole; DMAP / CH₂Cl₂ / 18 h

3.1: diisopropylamine; n-butyllithium / hexane; tetrahydrofuran / 1 h / -78 °C

3.2: 79 percent / tetrahydrofuran; hexane / 5 h / -78 - 20 °C

With 1H-imidazole; dmap; n-butyllithium; trimethylaluminum; diisopropylamine; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1021/ja004325r

Reference yield:

: 339046-99-0
(S)-3-Hydroxymethyl-pent-4-enoic acid diethylamide

: 339046-87-6
3-(tert-butyl-dimethyl-silanyloxymethyl)-2-[2-(tert-butyl-diphenyl-silanyloxy)-ethyl]-pent-4-enoic acid diethylamide

Guidance literature:: Multi-step reaction with 2 steps

1.1: 97 percent / imidazole; DMAP / CH₂Cl₂ / 18 h

2.1: diisopropylamine; n-butyllithium / hexane; tetrahydrofuran / 1 h / -78 °C

2.2: 79 percent / tetrahydrofuran; hexane / 5 h / -78 - 20 °C

With 1H-imidazole; dmap; n-butyllithium; diisopropylamine; In tetrahydrofuran; hexane; dichloromethane;
DOI:10.1021/ja004325r