diethylfluorophosphine sulfide

Base Information

• Chemical Name: diethylfluorophosphine sulfide
• CAS No.: 681-02-7
• Molecular Formula: C₄H₁₀FPS
• Molecular Weight: 140.162
• Mol file: 681-02-7.mol

Synonyms:diethylfluorophosphine sulfide

Chemical Property of diethylfluorophosphine sulfide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diethylfluorophosphine sulfide

There total 2 articles about diethylfluorophosphine sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

tetraethyldiphosphine disulfide (3790-23-6) + p-methoxybenzoyl fluoride (701-53-1) → diethyl(4-methoxybenzoyl)phosphine sulfide (1251445-53-0) + diethylfluorophosphine sulfide (681-02-7)

Guidance literature:

With hydridotetakis(triphenylphosphine)rhodium(I); bis(2-diphenylphosphinoethyl)phenylphosphine; for 4h; Inert atmosphere; Reflux;

DOI:10.1016/j.tetlet.2010.07.038

Reference yield: 87.0%

2,3,4,5,6-pentafluorobenzophenone (1536-23-8) + diethyl(4-(dimethylamino)benzoyl)phosphine sulfide (1251445-57-4) → diethylfluorophosphine sulfide (681-02-7) + 4-(dimethylamino)benzoyl fluoride (108168-59-8)

Guidance literature:

With hydridotetakis(triphenylphosphine)rhodium(I); depe; In chlorobenzene; for 4h; Inert atmosphere; Reflux;

DOI:10.1016/j.tet.2011.07.031

upstream raw materials:

tetraethyldiphosphine disulfide

p-methoxybenzoyl fluoride

2,3,4,5,6-pentafluorobenzophenone

diethyl(4-(dimethylamino)benzoyl)phosphine sulfide

Refernces

• 1、 Arisawa, Mieko,Yamada, Toru,Yamaguchi, Masahiko. "Synthesis of acylphosphine sulfides by rhodium-catalyzed reaction of acid fluorides and diphosphine disulfides". supporting information; experimental part. p. 4957 - 4958. Retrieved 2011/01/12.