phenyl 2-O-(4-azidobenzyl)-3-O-benzyl-4,6-O-benzylidene-1-thio-β-D-glucopyranoside

Base Information

Chemical Name:phenyl 2-O-(4-azidobenzyl)-3-O-benzyl-4,6-O-benzylidene-1-thio-β-D-glucopyranoside
CAS No.:1235579-94-8
Molecular Formula:C₃₃H₃₁N₃O₅S
Molecular Weight:581.692
Hs Code.:

Synonyms:phenyl 2-O-(4-azidobenzyl)-3-O-benzyl-4,6-O-benzylidene-1-thio-β-D-glucopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of phenyl 2-O-(4-azidobenzyl)-3-O-benzyl-4,6-O-benzylidene-1-thio-β-D-glucopyranoside

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Technology Process of phenyl 2-O-(4-azidobenzyl)-3-O-benzyl-4,6-O-benzylidene-1-thio-β-D-glucopyranoside

There total 1 articles about phenyl 2-O-(4-azidobenzyl)-3-O-benzyl-4,6-O-benzylidene-1-thio-β-D-glucopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 74489-49-9
4-azidobenzyl bromide

: 128848-51-1
phenyl 3-O-benzyl-4,6-O-benzylidene-1-deoxy-1-thio-β-D-glucopyranoside

: 1235579-94-8
phenyl 2-O-(4-azidobenzyl)-3-O-benzyl-4,6-O-benzylidene-1-thio-β-D-glucopyranoside

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; mineral oil; at 0 ℃; Inert atmosphere;
DOI:10.1016/j.bmc.2010.03.071

Reference yield:

: 1235579-94-8
phenyl 2-O-(4-azidobenzyl)-3-O-benzyl-4,6-O-benzylidene-1-thio-β-D-glucopyranoside

: 544686-87-5
(S)-(-)-1-allyl-3-tert-butyldiphenylsilyl-sn-glycerol

: 1-O-(tert-butyldiphenylsilyl)-2-O-(2-O-(4-azidobenzyl)-3-O benzyl-4,6-O-benzylidene-β-D-glucopyranosyl)-3-O-allyl-sn-glycerol

: 1235579-96-0
1-O-(tert-butyldiphenylsilyl)-2-O-(2-O-(4-azidobenzyl)-3-O benzyl-4,6-O-benzylidene-α-D-glucopyranosyl)-3-O-allyl-sn-glycerol

Guidance literature:: phenyl 2-O-(4-azidobenzyl)-3-O-benzyl-4,6-O-benzylidene-1-thio-β-D-glucopyranoside; With 1,1'-sulfinylbisbenzene; 2,4,6-tri-tert-butylpyrimidine; In dichloromethane; at -78 - 20 ℃; Inert atmosphere; Molecular sieve;

With trifluoromethylsulfonic anhydride; In dichloromethane; at -78 - -50 ℃; Inert atmosphere;

(S)-(-)-1-allyl-3-tert-butyldiphenylsilyl-sn-glycerol; In dichloromethane; at -75 ℃; for 1h; optical yield given as %de; Inert atmosphere;
DOI:10.1016/j.bmc.2010.03.071