2,3,3-triphenylpropenal tosylhydrazone

Base Information

• Chemical Name: 2,3,3-triphenylpropenal tosylhydrazone
• CAS No.: 87443-02-5
• Molecular Formula: C₂₈H₂₄N₂O₂S
• Molecular Weight: 452.577
• Mol file: 87443-02-5.mol

Synonyms:2,3,3-triphenylpropenal tosylhydrazone

Chemical Property of 2,3,3-triphenylpropenal tosylhydrazone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2,3,3-triphenylpropenal tosylhydrazone

There total 2 articles about 2,3,3-triphenylpropenal tosylhydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

2,3,3-triphenylacrylaldehyde (25683-83-4) + toluene-4-sulfonic acid hydrazide (1576-35-8) → 2,3,3-triphenylpropenal tosylhydrazone (87443-02-5)

Guidance literature:

With sulfuric acid; In methanol; for 0.333333h; Heating;

DOI:10.1021/ja00299a036

Reference yield:

2,3,3-triphenyl-prop-2-en-1-ol (94866-53-2) → 2,3,3-triphenylpropenal tosylhydrazone (87443-02-5)

Guidance literature:

Multi-step reaction with 2 steps

1: 97 percent / MnO₂ / benzene / 4 h

2: 80 percent / H₂SO₄ / methanol / 0.33 h / Heating

With manganese(IV) oxide; sulfuric acid; In methanol; benzene;

DOI:10.1021/ja00299a036

Reference yield: 78.0%

2,3,3-triphenylpropenal tosylhydrazone (87443-02-5) → 2,3-diphenyl-1H-indene (5324-00-5) + 1,1,3-triphenylpropa-1,2-diene (966-87-0) + 1,3,3-triphenylcyclopropene (87443-01-4)

Guidance literature:

With sodium methylate; In tetrahydrofuran; for 3.3h; Yields of byproduct given; Irradiation;

DOI:10.1021/ja00299a036

upstream raw materials:

2,3,3-triphenylacrylaldehyde

toluene-4-sulfonic acid hydrazide

2,3,3-triphenyl-prop-2-en-1-ol

Downstream raw materials:

2,3-diphenyl-1H-indene

1,1,3-triphenylpropa-1,2-diene

1,3,3-triphenylcyclopropene