Acetic acid (1R,3S,4R)-4-hydroxy-3-methyl-1-trityloxymethyl-hept-6-enyl ester

Base Information

Chemical Name:Acetic acid (1R,3S,4R)-4-hydroxy-3-methyl-1-trityloxymethyl-hept-6-enyl ester
CAS No.:900159-31-1
Molecular Formula:C₃₀H₃₄O₄
Molecular Weight:458.598
Hs Code.:

Synonyms:Acetic acid (1R,3S,4R)-4-hydroxy-3-methyl-1-trityloxymethyl-hept-6-enyl ester

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Chemical Property of Acetic acid (1R,3S,4R)-4-hydroxy-3-methyl-1-trityloxymethyl-hept-6-enyl ester

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Technology Process of Acetic acid (1R,3S,4R)-4-hydroxy-3-methyl-1-trityloxymethyl-hept-6-enyl ester

There total 9 articles about Acetic acid (1R,3S,4R)-4-hydroxy-3-methyl-1-trityloxymethyl-hept-6-enyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 900159-29-7
Acetic acid (1R,3S)-4-hydroxy-3-methyl-1-trityloxymethyl-butyl ester

: 900159-31-1
Acetic acid (1R,3S,4R)-4-hydroxy-3-methyl-1-trityloxymethyl-hept-6-enyl ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: 92 percent / Dess-Martin periodinane / CH₂Cl₂ / 0.5 h / 20 °C

2.1: (R,R)-1,2-diamino-1,2-diphenylethane-bis(toluenesulfonamide); boron tribromide / CH₂Cl₂ / 6 h / 20 °C

2.2: 85 percent / CH₂Cl₂ / 2 h / -78 °C

With (R,R)-1,2-diamino-1,2-diphenylethane-bis(toluenesulfonamide); boron tribromide; Dess-Martin periodane; In dichloromethane;
DOI:10.1021/jo0605086

Reference yield:

: 900159-10-6
(2R,4S)-5-(tert-Butyl-dimethyl-silanyloxy)-4-methyl-1-trityloxy-pentan-2-ol

: 900159-31-1
Acetic acid (1R,3S,4R)-4-hydroxy-3-methyl-1-trityloxymethyl-hept-6-enyl ester

Guidance literature:: Multi-step reaction with 4 steps

1.1: 99 percent / Et₃N; 4-(dimethylamino)pyridine / CH₂Cl₂ / 12 h / 20 °C

2.1: 96 percent / tetrabutylammonium fluoride / tetrahydrofuran / 20 °C

3.1: 92 percent / Dess-Martin periodinane / CH₂Cl₂ / 0.5 h / 20 °C

4.1: (R,R)-1,2-diamino-1,2-diphenylethane-bis(toluenesulfonamide); boron tribromide / CH₂Cl₂ / 6 h / 20 °C

4.2: 85 percent / CH₂Cl₂ / 2 h / -78 °C

With dmap; (R,R)-1,2-diamino-1,2-diphenylethane-bis(toluenesulfonamide); tetrabutyl ammonium fluoride; boron tribromide; Dess-Martin periodane; triethylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo0605086

Reference yield:

: 900159-28-6
Acetic acid (1R,3S)-4-(tert-butyl-dimethyl-silanyloxy)-3-methyl-1-trityloxymethyl-butyl ester

: 900159-31-1
Acetic acid (1R,3S,4R)-4-hydroxy-3-methyl-1-trityloxymethyl-hept-6-enyl ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: 96 percent / tetrabutylammonium fluoride / tetrahydrofuran / 20 °C

2.1: 92 percent / Dess-Martin periodinane / CH₂Cl₂ / 0.5 h / 20 °C

3.1: (R,R)-1,2-diamino-1,2-diphenylethane-bis(toluenesulfonamide); boron tribromide / CH₂Cl₂ / 6 h / 20 °C

3.2: 85 percent / CH₂Cl₂ / 2 h / -78 °C

With (R,R)-1,2-diamino-1,2-diphenylethane-bis(toluenesulfonamide); tetrabutyl ammonium fluoride; boron tribromide; Dess-Martin periodane; In tetrahydrofuran; dichloromethane;
DOI:10.1021/jo0605086