iron(III) tetraphenylporphyrin

Base Information

• Chemical Name: iron(III) tetraphenylporphyrin
• CAS No.: 29484-63-7
• Molecular Formula: C₄₄H₂₈FeN₄
• Molecular Weight: 668.58
• Mol file: 29484-63-7.mol

Synonyms:iron(III) tetraphenylporphyrin

Chemical Property of iron(III) tetraphenylporphyrin

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of iron(III) tetraphenylporphyrin

There total 2 articles about iron(III) tetraphenylporphyrin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

((5,10,15,20-tetraphenylporphyrinato)iron(III))2O (12582-61-5) → iron(III) tetraphenylporphyrin (29484-63-7) + 5,10,15,20-tetraphenyl porphyrin iron (16591-56-3) + Fe(IV)=O(tetraphenylporphinate) (84152-32-9) + TPPFe(III)-O(1-) (115162-51-1)

Guidance literature:

In benzene; Irradiation (UV/VIS); photoexcitation (single 532 or 355-nm 25-ps FWHM pulse); determination with picosecond absorption spectroscopy, total yield no more than about 1E-4 (80% of TPPFe(1+) and TPPFe-O(1-));

DOI:10.1021/ja00224a006

Reference yield:

5,10,15,20-tetraphenyl-21H,23H-porphine (917-23-7,20998-75-8) + iron(III) acetate (1834-30-6,2140-52-5,3094-87-9) → iron(III) tetraphenylporphyrin (29484-63-7)

Guidance literature:

In N,N-dimethyl-formamide;

DOI:10.1007/BF00961258

Reference yield:

iron(III) tetraphenylporphyrin (29484-63-7) → 5,10,15,20-tetraphenyl porphyrin iron (16591-56-3) + 5,10,15,20-tetraphenyl porphyrinato iron hydroxide (25482-26-2)

Guidance literature:

With hydroxide; In pyridine; N,N-dimethyl-formamide; addition of OH(1-) to soln. of complex in mixt. of pyridine and DMF; UV, cyclic voltammetry;

upstream raw materials:

5,10,15,20-tetraphenyl-21H,23H-porphine

iron(III) acetate

((5,10,15,20-tetraphenylporphyrinato)iron(III))2O

Downstream raw materials:

5,10,15,20-tetraphenyl porphyrin iron

5,10,15,20-tetraphenyl porphyrinato iron hydroxide