(2R,3R)-3-Methyl-5-triisopropylsilanyloxy-2-triphenylsilanyloxy-pentanal

Base Information

Chemical Name:(2R,3R)-3-Methyl-5-triisopropylsilanyloxy-2-triphenylsilanyloxy-pentanal
CAS No.:500102-84-1
Molecular Formula:C₃₃H₄₆O₃Si₂
Molecular Weight:546.897
Hs Code.:

Synonyms:(2R,3R)-3-Methyl-5-triisopropylsilanyloxy-2-triphenylsilanyloxy-pentanal

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Chemical Property of (2R,3R)-3-Methyl-5-triisopropylsilanyloxy-2-triphenylsilanyloxy-pentanal

Chemical Property:

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Technology Process of (2R,3R)-3-Methyl-5-triisopropylsilanyloxy-2-triphenylsilanyloxy-pentanal

There total 8 articles about (2R,3R)-3-Methyl-5-triisopropylsilanyloxy-2-triphenylsilanyloxy-pentanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: 500103-05-9
(2R,3R)-3-Methyl-5-triisopropylsilanyloxy-2-triphenylsilanyloxy-pentanoic acid ethyl ester

: 500102-84-1
(2R,3R)-3-Methyl-5-triisopropylsilanyloxy-2-triphenylsilanyloxy-pentanal

Guidance literature:: With diisobutylaluminium hydride; In toluene; at -78 ℃;
DOI:10.1002/1521-3773(20021202)41:23<4560::AID-ANIE4560>3.0.CO;2-B

Reference yield:

: 76-86-8
Triphenylsilyl chloride

: 500102-84-1
(2R,3R)-3-Methyl-5-triisopropylsilanyloxy-2-triphenylsilanyloxy-pentanal

Guidance literature:: Multi-step reaction with 7 steps

1: 98 percent / imidazole; 4-(N,N-dimethylamino)pyridine / dimethylformamide / 0 °C

2: 95 percent / Et₃SiH / Pd/C / acetone

3: 84 percent / Zn; [(cyclopentadienyl)2ZrCl₂] / tetrahydrofuran / 0 °C

4: [(Ph₃P)3RhCl] / tetrahydrofuran / 0 °C

5: H₂O₂ / ethanol / pH 7

6: 100 percent / 2,6-lutidine / CH₂Cl₂ / -78 °C

7: 89 percent / DIBAL-H / toluene / -78 °C

With 1H-imidazole; 2,6-dimethylpyridine; triethylsilane; dmap; Wilkinson's catalyst; zirconocene dichloride; dihydrogen peroxide; diisobutylaluminium hydride; zinc; palladium on activated charcoal; In tetrahydrofuran; ethanol; dichloromethane; N,N-dimethyl-formamide; acetone; toluene;
DOI:10.1002/1521-3773(20021202)41:23<4560::AID-ANIE4560>3.0.CO;2-B

Reference yield:

: 246510-31-6
(2R,3S)-2-Hydroxy-3-phenylsulfanylcarbonyl-butyric acid ethyl ester

: 500102-84-1
(2R,3R)-3-Methyl-5-triisopropylsilanyloxy-2-triphenylsilanyloxy-pentanal

Guidance literature:: Multi-step reaction with 7 steps

1: 98 percent / imidazole; 4-(N,N-dimethylamino)pyridine / dimethylformamide / 0 °C

2: 95 percent / Et₃SiH / Pd/C / acetone

3: 84 percent / Zn; [(cyclopentadienyl)2ZrCl₂] / tetrahydrofuran / 0 °C

4: [(Ph₃P)3RhCl] / tetrahydrofuran / 0 °C

5: H₂O₂ / ethanol / pH 7

6: 100 percent / 2,6-lutidine / CH₂Cl₂ / -78 °C

7: 89 percent / DIBAL-H / toluene / -78 °C

With 1H-imidazole; 2,6-dimethylpyridine; triethylsilane; dmap; Wilkinson's catalyst; zirconocene dichloride; dihydrogen peroxide; diisobutylaluminium hydride; zinc; palladium on activated charcoal; In tetrahydrofuran; ethanol; dichloromethane; N,N-dimethyl-formamide; acetone; toluene;
DOI:10.1002/1521-3773(20021202)41:23<4560::AID-ANIE4560>3.0.CO;2-B