5,10-bis(3,5-di-t-butylphenyl)-15-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrin zinc(II) complex

Base Information

Chemical Name:5,10-bis(3,5-di-t-butylphenyl)-15-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrin zinc(II) complex
CAS No.:1072782-61-6
Molecular Formula:C₅₄H₆₃BN₄O₂Zn
Molecular Weight:876.321
Hs Code.:

Synonyms:5,10-bis(3,5-di-t-butylphenyl)-15-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrin zinc(II) complex

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Chemical Property of 5,10-bis(3,5-di-t-butylphenyl)-15-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrin zinc(II) complex

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Technology Process of 5,10-bis(3,5-di-t-butylphenyl)-15-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrin zinc(II) complex

There total 3 articles about 5,10-bis(3,5-di-t-butylphenyl)-15-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrin zinc(II) complex which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 1187734-91-3
[5,10-bis(3,5-di-tert-butylphenyl)-15,20-dibromoporphyrinato]zinc(II)

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 832079-41-1
C₄₈H₅₂N₄Zn

: 1072782-61-6
[5,10-bis(3,5-di-tert-butylphenyl)-15-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrinato]zinc(II)

: 1187734-92-4
5,10-bis[3,5-di(tert-butyl)phenyl]-15,20-bis(4,4,5,5-tetramethyl-[1,3,2]dioxaborolan-2-yl)porphyrinato-N⁽²¹⁾,N⁽²²⁾,N⁽²³⁾,N⁽²⁴⁾zinc(II)

Guidance literature:: With bis-triphenylphosphine-palladium(II) chloride; triethylamine; In 1,2-dichloro-ethane; for 2h; Reflux; Inert atmosphere;
DOI:10.1002/chem.200800776

Reference yield: 66.0%

: 5,10-bis(3,5-di-tert-butylphenyl)porphyrin

: 25015-63-8
4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane

: 1072782-61-6
5,10-bis(3,5-di-t-butylphenyl)-15-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrin zinc(II) complex

Guidance literature:: 5,10-bis(3,5-di-tert-butylphenyl)porphyrin; With pyridine; N-Bromosuccinimide; In dichloromethane; at 0 ℃; for 3h; Inert atmosphere;

With zinc diacetate; In methanol; chloroform; at 20 ℃; for 3h;

4,4,5,5-tetramethyl-[1,3,2]-dioxaboralane; With bis-triphenylphosphine-palladium(II) chloride; triethylamine; In 1,2-dichloro-ethane; for 2h; Reflux; Inert atmosphere;
DOI:10.1039/b807351a

Reference yield: 66.0%

: 128-08-5
N-Bromosuccinimide

: 5,10-di(3,5-di-tert-butylphenyl)porphyrin

: 557-34-6
zinc diacetate

: 1072782-61-6
5,10-bis(3,5-di-t-butylphenyl)-15-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)porphyrin zinc(II) complex

Guidance literature:: With Pd⁽⁰⁾ catalyst; In not given; three step reaction; NBS (1.3 equiv.) bromination, Zn insertion, Pd(0)-cat. borylation (according to A. G. Hyslop et al., J. Am. Chem. Soc. (1998), vol 120, p. 12676);
DOI:10.1039/b807351a