Technology Process of trans-CH3OIr(CO)(P(p-tolyl)3)2
There total 2 articles about trans-CH3OIr(CO)(P(p-tolyl)3)2 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
tetrahydrofuran;
stirring for 17 h at ambient temp. in a drybox under Ar; removal of solvent, dissoln. in toluene, removal of toluene in vacuo, extn.with benzene, filtn., removal of benzene, dissoln. in Et2O/THF, addn. of hexanes, redn. of vol., vacuum filtn., washing with hexanes; elem. anal.;
DOI:10.1021/om00099a007
- Guidance literature:
-
Multi-step reaction with 2 steps
1: benzene-d6
2: tetrahydrofuran
In
tetrahydrofuran; benzene-d6;
DOI:10.1021/om00099a007
- Guidance literature:
-
With
water;
In
tetrahydrofuran;
(Ar or N2), trans-Ir(CO)(OCH3)(P(p-tolyl)3)2 dissolved in THF, H2O added, stirred at room temp. for 16 h; solvent removed, solid dissolved in toluene, removed, solid extracted with benzene, filtered, hexane added, crystals collected, washed with hexane, elem. anal.;
