trans-CH₃OIr(CO)(P(p-tolyl)3)2

Base Information

Chemical Name:trans-CH₃OIr(CO)(P(p-tolyl)3)2
CAS No.:115338-91-5
Molecular Formula:C₄₄H₄₅IrO₂P₂
Molecular Weight:860.008
Hs Code.:

trans-CH<sub>3</sub>OIr(CO)(P(p-tolyl)3)2

Synonyms:trans-CH₃OIr(CO)(P(p-tolyl)3)2

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Chemical Property of trans-CH₃OIr(CO)(P(p-tolyl)3)2

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Technology Process of trans-CH₃OIr(CO)(P(p-tolyl)3)2

There total 2 articles about trans-CH₃OIr(CO)(P(p-tolyl)3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 28195-56-4
trans-carbonylchloro-bis(tri-(p-tolyl)phosphine)iridium(I)

: 124-41-4
sodium methylate

: 115338-91-5
trans-CH₃OIr(CO)(P(p-tolyl)3)2

Guidance literature:: In tetrahydrofuran; stirring for 17 h at ambient temp. in a drybox under Ar; removal of solvent, dissoln. in toluene, removal of toluene in vacuo, extn.with benzene, filtn., removal of benzene, dissoln. in Et2O/THF, addn. of hexanes, redn. of vol., vacuum filtn., washing with hexanes; elem. anal.;
DOI:10.1021/om00099a007

Reference yield:

: 115338-92-6
trans-C₆H₅OIr(CO)(P(p-tolyl)3)2

: 115338-91-5
trans-CH₃OIr(CO)(P(p-tolyl)3)2

Guidance literature:: Multi-step reaction with 2 steps

1: benzene-d6

2: tetrahydrofuran

In tetrahydrofuran; benzene-d6;
DOI:10.1021/om00099a007

Reference yield: 65.0%

: 115338-91-5
trans-CH₃OIr(CO)(P(p-tolyl)3)2

: 132854-92-3
Ir(CO)(OH)(P(C₆H₄CH₃)3)2

Guidance literature:: With water; In tetrahydrofuran; (Ar or N2), trans-Ir(CO)(OCH3)(P(p-tolyl)3)2 dissolved in THF, H2O added, stirred at room temp. for 16 h; solvent removed, solid dissolved in toluene, removed, solid extracted with benzene, filtered, hexane added, crystals collected, washed with hexane, elem. anal.;