4-BROMO-2-METHOXYBENZOIC ACID ETHYL ESTER

Base Information

Chemical Name:4-BROMO-2-METHOXYBENZOIC ACID ETHYL ESTER
CAS No.:1214366-76-3
Molecular Formula:C₁₀H₁₁BrO₃
Molecular Weight:259.1
Hs Code.:
Mol file:1214366-76-3.mol

Synonyms:ethyl 4-bromo-2-methoxybenzoate

Suppliers and Price of 4-BROMO-2-METHOXYBENZOIC ACID ETHYL ESTER

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Crysdot
4-Bromo-2-methoxybenzoicacidethylester 95+%
1g
$ 313.00

Alichem
Ethyl4-bromo-2-methoxybenzoate
1g
$ 1504.90

Alichem
Ethyl4-bromo-2-methoxybenzoate
500mg
$ 806.85

Alichem
Ethyl4-bromo-2-methoxybenzoate
250mg
$ 470.40

AHH
ethyl4-bromo-2-methoxybenzoate 97%
1g
$ 458.00

Total 2 raw suppliers

Chemical Property of 4-BROMO-2-METHOXYBENZOIC ACID ETHYL ESTER

Chemical Property:

Purity/Quality:

99% ^*data from raw suppliers

4-Bromo-2-methoxybenzoicacidethylester 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 4-BROMO-2-METHOXYBENZOIC ACID ETHYL ESTER

There total 2 articles about 4-BROMO-2-METHOXYBENZOIC ACID ETHYL ESTER which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 314240-85-2
ethyl 4-bromo-2-hydroxybenzoate

: 74-88-4
methyl iodide

: 1214366-76-3
ethyl 4-bromo-2-methoxybenzoate

Guidance literature:: With potassium carbonate; In N,N-dimethyl-formamide; at 20 ℃; for 2h;
DOI:10.1021/ol301104n

Reference yield:

: 5798-75-4
Ethyl 4-bromobenzoate

: 1214366-76-3
ethyl 4-bromo-2-methoxybenzoate

Guidance literature:: Multi-step reaction with 2 steps

1: [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; Selectfluor; trifluoroacetic acid; trifluoroacetic anhydride / 5.5 h / 110 °C

2: potassium carbonate / N,N-dimethyl-formamide / 2 h / 20 °C

With [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; potassium carbonate; Selectfluor; trifluoroacetic acid; trifluoroacetic anhydride; In N,N-dimethyl-formamide;
DOI:10.1021/ol301104n

Reference yield: 71.0%

: 1214366-76-3
ethyl 4-bromo-2-methoxybenzoate

: 1376702-05-4
ethyl 4-bromo-2-hydroxy-6-methoxybenzoate

Guidance literature:: With dipotassium peroxodisulfate; [ruthenium(II)(η⁶-1-methyl-4-isopropyl-benzene)(chloride)(μ-chloride)]₂; trifluoroacetic acid; trifluoroacetic anhydride; at 80 ℃; for 11h;
DOI:10.1021/ol301104n