(2S,3S)-2-(2-Nitro-benzyloxymethyl)-3-(4-trifluoromethyl-phenyl)-oxirane

Base Information

Chemical Name:(2S,3S)-2-(2-Nitro-benzyloxymethyl)-3-(4-trifluoromethyl-phenyl)-oxirane
CAS No.:757190-34-4
Molecular Formula:C₁₇H₁₄F₃NO₄
Molecular Weight:353.298
Hs Code.:

Synonyms:(2S,3S)-2-(2-Nitro-benzyloxymethyl)-3-(4-trifluoromethyl-phenyl)-oxirane

Suppliers and Price of (2S,3S)-2-(2-Nitro-benzyloxymethyl)-3-(4-trifluoromethyl-phenyl)-oxirane

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2S,3S)-2-(2-Nitro-benzyloxymethyl)-3-(4-trifluoromethyl-phenyl)-oxirane

Chemical Property:

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Technology Process of (2S,3S)-2-(2-Nitro-benzyloxymethyl)-3-(4-trifluoromethyl-phenyl)-oxirane

There total 2 articles about (2S,3S)-2-(2-Nitro-benzyloxymethyl)-3-(4-trifluoromethyl-phenyl)-oxirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 24.0%

: 757190-48-0
(2S,3S)-2,3-epoxy-3-(4-trifluoromethylphenyl)propan-1-ol

: 757190-34-4
(2S,3S)-2-(2-Nitro-benzyloxymethyl)-3-(4-trifluoromethyl-phenyl)-oxirane

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; at -20 ℃;
DOI:10.1016/j.tetlet.2004.06.069

Reference yield:

: 125617-18-7
3-(4-trifluoromethylphenyl)-2-propen-1-ol

: 757190-34-4
(2S,3S)-2-(2-Nitro-benzyloxymethyl)-3-(4-trifluoromethyl-phenyl)-oxirane

Guidance literature:: Multi-step reaction with 2 steps

1: 89 percent / tBuOOH; L-(+)-DIPT; Ti(OiPr)4 / CH₂Cl₂

2: 24 percent / NaH / dimethylformamide / -20 °C

With titanium(IV) isopropylate; tert.-butylhydroperoxide; L-(+)-diisopropyl tartrate; sodium hydride; In dichloromethane; N,N-dimethyl-formamide; 1: Sharpless epoxidation;
DOI:10.1016/j.tetlet.2004.06.069