benzyl 5,6-dimethylpicolinate

Base Information

Chemical Name:benzyl 5,6-dimethylpicolinate
CAS No.:1416255-29-2
Molecular Formula:C₁₅H₁₅NO₂
Molecular Weight:241.29
Hs Code.:

Synonyms:benzyl 5,6-dimethylpicolinate

Suppliers and Price of benzyl 5,6-dimethylpicolinate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of benzyl 5,6-dimethylpicolinate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of benzyl 5,6-dimethylpicolinate

There total 3 articles about benzyl 5,6-dimethylpicolinate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 2495-35-4,25036-21-9
benzylacrylate

: 1416255-75-8
(E)-3-methylbut-3-en-2-one O-pivaloyl oxime

: 1416255-29-2
benzyl 5,6-dimethylpicolinate

Guidance literature:: With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; silver(I) acetate; In acetic acid; 1,2-dichloro-ethane; at 85 ℃; for 14h; regioselective reaction; Inert atmosphere;
DOI:10.1021/ja3104389

Reference yield:

: 814-78-8,25988-32-3
3-Methyl-3-buten-2-one

: 1416255-29-2
benzyl 5,6-dimethylpicolinate

Guidance literature:: Multi-step reaction with 3 steps

1: hydroxylamine hydrochloride; sodium carbonate / methanol / 1 h / 65 °C / Inert atmosphere

2: triethylamine / dichloromethane / 0 °C / Inert atmosphere

3: silver(I) acetate; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer / 1,2-dichloro-ethane; acetic acid / 14 h / 85 °C / Inert atmosphere

With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; hydroxylamine hydrochloride; silver(I) acetate; sodium carbonate; triethylamine; In methanol; dichloromethane; acetic acid; 1,2-dichloro-ethane;
DOI:10.1021/ja3104389

Reference yield:

: 28051-69-6
3-methyl-but-3-en-2-one (E)-oxime

: 1416255-29-2
benzyl 5,6-dimethylpicolinate

Guidance literature:: Multi-step reaction with 2 steps

1: triethylamine / dichloromethane / 0 °C / Inert atmosphere

2: silver(I) acetate; dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer / 1,2-dichloro-ethane; acetic acid / 14 h / 85 °C / Inert atmosphere

With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; silver(I) acetate; triethylamine; In dichloromethane; acetic acid; 1,2-dichloro-ethane;
DOI:10.1021/ja3104389