9-phenyl-8,9,10,11,19,20-hexahydro-5H,7H,13H-18,21-dioxa-6,12-dithia-9-aza-dibenzo[a,g]cycloheptadecene

Base Information

• Chemical Name: 9-phenyl-8,9,10,11,19,20-hexahydro-5H,7H,13H-18,21-dioxa-6,12-dithia-9-aza-dibenzo[a,g]cycloheptadecene
• CAS No.: 887626-77-9
• Molecular Formula: C₂₆H₂₉NO₂S₂
• Molecular Weight: 451.654

Synonyms:9-phenyl-8,9,10,11,19,20-hexahydro-5H,7H,13H-18,21-dioxa-6,12-dithia-9-aza-dibenzo[a,g]cycloheptadecene

Chemical Property of 9-phenyl-8,9,10,11,19,20-hexahydro-5H,7H,13H-18,21-dioxa-6,12-dithia-9-aza-dibenzo[a,g]cycloheptadecene

Chemical Property:

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Technology Process of 9-phenyl-8,9,10,11,19,20-hexahydro-5H,7H,13H-18,21-dioxa-6,12-dithia-9-aza-dibenzo[a,g]cycloheptadecene

There total 3 articles about 9-phenyl-8,9,10,11,19,20-hexahydro-5H,7H,13H-18,21-dioxa-6,12-dithia-9-aza-dibenzo[a,g]cycloheptadecene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 48.0%

2,2'-(phenylazanediyl)diethanethiol (35225-26-4) + 2,2'-(ethylenedioxy)bis(benzyl chloride) (156339-64-9) → 9-phenyl-8,9,10,11,19,20-hexahydro-5H,7H,13H-18,21-dioxa-6,12-dithia-9-aza-dibenzo[a,g]cycloheptadecene (887626-77-9)

Guidance literature:

With caesium carbonate; In N,N-dimethyl-formamide; at 45 - 50 ℃; for 15h;

DOI:10.1021/ol0602405

Reference yield:

2,2'-(phenylimino)bis[ethanol] (120-07-0) → 9-phenyl-8,9,10,11,19,20-hexahydro-5H,7H,13H-18,21-dioxa-6,12-dithia-9-aza-dibenzo[a,g]cycloheptadecene (887626-77-9)

Guidance literature:

Multi-step reaction with 3 steps

1.1: 81.7 percent / pyridine / 3 h / 20 °C

2.1: thiourea / ethanol / 2 h / Heating

2.2: 87 percent / H₂O; NaHCO₃ / ethanol / 3 h / Heating

3.1: 48 percent / cesium carbonate / dimethylformamide / 15 h / 45 - 50 °C

With pyridine; caesium carbonate; thiourea; In ethanol; N,N-dimethyl-formamide;

DOI:10.1021/ol0602405

Reference yield:

N,N-bis(2-p-tolylsulfonyloxyethyl)aniline (3590-12-3) → 9-phenyl-8,9,10,11,19,20-hexahydro-5H,7H,13H-18,21-dioxa-6,12-dithia-9-aza-dibenzo[a,g]cycloheptadecene (887626-77-9)

Guidance literature:

Multi-step reaction with 2 steps

1.1: thiourea / ethanol / 2 h / Heating

1.2: 87 percent / H₂O; NaHCO₃ / ethanol / 3 h / Heating

2.1: 48 percent / cesium carbonate / dimethylformamide / 15 h / 45 - 50 °C

With caesium carbonate; thiourea; In ethanol; N,N-dimethyl-formamide;

DOI:10.1021/ol0602405

upstream raw materials:

2,2'-(phenylazanediyl)diethanethiol

2,2'-(ethylenedioxy)bis(benzyl chloride)

2,2'-(phenylimino)bis[ethanol]

N,N-bis(2-p-tolylsulfonyloxyethyl)aniline

Downstream raw materials:

C₃₁H₂₈N₄O₂S₂

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