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(Phenylimino)diethane-2,1-diyl bis(4-methylbenzenesulfonate) is a chemical compound characterized by its molecular formula C26H28N2O10S2. It is a sulfonate ester derived from phenylimine and diethane-2,1-diyl bis(4-methylbenzenesulfonate), known for its applications in organic synthesis and as a reactive intermediate in the production of pharmaceuticals and agrochemicals. (phenylimino)diethane-2,1-diyl bis(4-methylbenzenesulfonate) also serves as a reagent in chemical reactions, particularly in the formation of carbon-carbon bonds. However, it is essential to handle and store this chemical with care due to its potentially hazardous properties, such as being harmful if swallowed or inhaled.

3590-12-3

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3590-12-3 Usage

Uses

Used in Organic Synthesis:
(Phenylimino)diethane-2,1-diyl bis(4-methylbenzenesulfonate) is used as a key component in organic synthesis for the creation of various chemical compounds. Its unique structure allows it to participate in a range of reactions, making it a valuable asset in the field of chemistry.
Used in Pharmaceutical Production:
In the pharmaceutical industry, (phenylimino)diethane-2,1-diyl bis(4-methylbenzenesulfonate) is utilized as a reactive intermediate. Its role in the synthesis of specific drugs contributes to the development of new medications and therapies.
Used in Agrochemical Production:
Similarly, in the agrochemical sector, (phenylimino)diethane-2,1-diyl bis(4-methylbenzenesulfonate) is employed as an intermediate in the production of various agrochemicals, such as pesticides and fertilizers, which are essential for agricultural productivity.
Used as a Reagent in Chemical Reactions:
(Phenylimino)diethane-2,1-diyl bis(4-methylbenzenesulfonate) is also used as a reagent in chemical reactions, particularly those involving the formation of carbon-carbon bonds. Its participation in these reactions aids in the synthesis of complex organic molecules.
Safety Precautions:
Due to its potentially hazardous properties, it is crucial to handle and store (phenylimino)diethane-2,1-diyl bis(4-methylbenzenesulfonate) with caution and in accordance with safety guidelines. This includes using appropriate personal protective equipment (PPE) and ensuring proper ventilation during its use.

Check Digit Verification of cas no

The CAS Registry Mumber 3590-12-3 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,5,9 and 0 respectively; the second part has 2 digits, 1 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 3590-12:
(6*3)+(5*5)+(4*9)+(3*0)+(2*1)+(1*2)=83
83 % 10 = 3
So 3590-12-3 is a valid CAS Registry Number.

3590-12-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 14, 2017

Revision Date: Aug 14, 2017

1.Identification

1.1 GHS Product identifier

Product name (phenylimino)diethane-2,1-diyl bis(4-methylbenzenesulfonate)

1.2 Other means of identification

Product number -
Other names Ethanol, 2,2'- (phenylimino)bis-, bis(4-methylbenzenesulfonate)

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:3590-12-3 SDS

3590-12-3Relevant articles and documents

Selective Detection of Cu+ Ions in Live Cells via Fluorescence Lifetime Imaging Microscopy

Kuimova, Marina K.,Lewis, Benjamin W.,Priessner, Martin,Sastre, Magdalena,Summers, Peter A.,Vilar, Ramon,Ying, Liming

supporting information, p. 23148 - 23153 (2021/09/20)

Copper is an essential trace element in living organisms with its levels and localisation being carefully managed by the cellular machinery. However, if misregulated, deficiency or excess of copper ions can lead to several diseases. Therefore, it is impor

Tracking Labile Copper Fluctuation in Vivo/ Ex Vivo: Design and Application of a Ratiometric Near-Infrared Fluorophore Derived from 4-Aminostyrene-Conjugated Boron Dipyrromethene

Xu, Hongxia,Yao, Shankun,Chen, Yuncong,Zhang, Changli,Zhang, Shuren,Yuan, Hao,Chen, Zhongyan,Bai, Yang,Yang, Tao,Guo, Zijian,He, Weijiang

, p. 18567 - 18574 (2021/12/09)

Specimen differences, tissue-dependent background fluorescence and scattering, and deviated specimen position and sensor concentration make optical imaging for labile copper fluctuation in animals questionable, and a signal comparison between specimens is

Redox triggered aggregation induced emission (AIE) polymers with azobenzene pendants

Wu, Bing,Wang, Wei,Wang, Jilei,Li, Shang,He, Yaning

, p. 290 - 297 (2018/05/24)

We reported the redox triggered aggregation induced emission (AIE) polymers with azobenzene pendants. Tetraphenylethene (TPE) based polymers with selected degrees of functionalization of azobenzene chromophores were synthesized through a post-polymerizati

Synthesis, characterization and theoretical investigations of molybdenum carbonyl complexes with phosphorus/nitrogen/phosphorus ligand as bidentate and tridentate modes

Goren Keskin, Seyma,Stanley, Julie M.,Cowley, Alan H.

, p. 206 - 217 (2017/10/16)

Carbonyl complexes of molybdenum with the phosphorus/nitrogen/phosphorus ligand, PNP-Mo(CO)n, where n = 3, 4 and PNP is N,N-bis[2-(diphenylphosphino)ethyl]phenylamine have been synthesized and characterized by 1H, 31P{1H} NMR, IR (ATR and solution state), Raman, X-ray diffraction, MS and elemental analysis. DFT calculations of the complexes were also performed. The PNP-Mo(CO)4 complex in which the binding mode is bidentate cis-phosphine and, facial and meridional isomers of PNP-Mo(CO)3 in which the binding mode is tridentate were obtained. The facial isomer and the tetracarbonyl complexes were successfully synthesized and purified; however, it was not possible to isolate the meridional isomer. Only a few crystals of the meridional isomer were detected and used for X-ray analysis. When the facial isomer was dissolved in CH2Cl2 or in THF, it was found to undergo decomposition thereby generating the tetracarbonyl complex, meridional isomer, Mo(0) as a dark precipitate along with some facial isomer that was left intact in solution. The reason that the facial isomer was the preferred structure with respect to the meridional isomer was also investigated.

Molybdenum dinitrogen complexes facially coordinated by linear tridentate PEP ligands (E = N or P): Impact of the central e donor in: Trans -position to N2

Hinrichsen, Svea,Schnoor, Ann-Christin,Grund, Katharina,Fl?ser, Benedikt,Schlimm, Alexander,N?ther, Christian,Krahmer, Jan,Tuczek, Felix

supporting information, p. 14801 - 14813 (2016/09/28)

The syntheses of molybdenum dinitrogen complexes supported by the tridentate PEP ligands (E = N, P) prPP(Ph)P = (Ph2PCH2CH2CH2)2P(Ph), prPPHP = (Ph2PCH2CH2CH2)2PH, PN(Ph)P = (Ph2PCH2CH2)2N(Ph) and prPN(Ph)P = (Ph2PCH2CH2CH2)2N(Ph) are reported. Together with the coligand dmpm = (CH3)2PCH2P(CH3)2 dinitrogen complexes of the type [Mo(N2)(PEP)(dmpm)] are formed. The new systems are characterized by IR and NMR spectroscopy and compared with the literature-known complex [Mo(N2)(dpepp)(dmpm)] (1) (dpepp = PhP(CH2CH2PPh2)2). The consequences of the substitution of the central P-donor of dpepp by N and the replacement of its C2 by C3 linkages as well as the exchange of the EPh by an EH function are investigated with respect to the stability of the corresponding N2-complexes. Importantly, the activation of the N2 ligand drastically increases upon replacing the trans-phosphine with a trans-amine donor.

α-Glucosidase inhibition and antihyperglycemic activity of flavonoids from Ampelopsis grossedentata and the flavonoid derivatives

Chen, Jia,Wu, Yuechan,Zou, Jianwei,Gao, Kun

, p. 1488 - 1494 (2016/03/16)

The dried leaves and stems of Ampelopsis grossedentata have been used as a health tea and herbal medicine for hundreds of years in China. The study was aimed at searching for novel α-glucosidase inhibitors among the richest components of A. grossedentata and their derivatives. Three known major components (1-3) were isolated by recrystallization process and six new derivatives (4-9) were obtained by etherification of the bioactive flavonoid. All compounds were evaluated for their inhibitory activities against α-glucosidase (from Saccharomyces cerevisiae). As a result, compound 9 showed a significant α-glucosidase inhibitory activity with IC50 value of 9.3 μM and acted as a competitive inhibitor with the value of the inhibition constant (Ki) being 10.3 μM. The oral administration of compound 9 at a dose of 50 mg/kg significantly reduced the post prandial blood glucose levels of normal and streptozotocin (STZ)-induced diabetic mice. Furthermore, compound 9 significantly decreased the fasting blood glucose levels in STZ-induced diabetic mice.

Synthesis of New Bis-1,2,4-Oxadiazoline Derivatives via 1,3-Dipolar Cycloaddition Reaction

Chen, Fei,Zeng, Hua,Liu, Fang-Ming

, p. 1866 - 1870 (2016/11/23)

A series of novel bis-oxadiazoline derivatives 4 was synthesized via 1,3-dipolar cycloaddition reaction of bis-aldimines 3, and nitrile oxides generated in situ from various benzohydroximinoyl chlorides in the presence of Et3N. The target products were confirmed by IR,1H-NMR, and mass spectrometry.

Synthesis and spectroscopic properties of new bis-tetrazoles

Pazik, Agnieszka,Skwierawska, Anna

, p. 83 - 94 (2014/01/06)

Syntheses of N,N′-phenyltetrazole podands link with aliphatic chains containing oxygen, nitrogen and sulphur atoms, are described. The complexing properties of these compounds towards metal cations (Fe2+, Cu 2+, Zn2+, Co2+, Ni2+) were investigated by absorption and infrared spectroscopy. The UV-Vis titrations were performed to estimate the stability constant values of the respective complexes with Cu2+ ion. Changes in UV-Vis absorption spectra and IR spectra of compound 6 under various concentrations of Cu2+ ion in methanol suggest formation of very unstable complex. The structure of ligand 2 has been deduced by X-ray crystallography. The Author(s) 2012.

A Carbazole-attached NO2S2-macrocycle exhibiting Hg2+ and Cu2+ selectivity

Lee, Seul-Gi,Kang, Eun-Ju,Lee, Shim Sung

, p. 1429 - 1434 (2013/07/28)

A synthesis and cation-induced fluorescent behavior of the carbazole-attached NO2S2-macrocycle (L) is described and structurally characterized by single crystal X-ray analysis. The photoluminescence spectrum of L in 80% CH3/sub

Steady-state and time-resolved investigations of a crown thioether conjugated with methylacridinium and its complexes with metal ions

Giacco, Tiziana Del,Carlotti, Benedetta,Solis, Stefano De,Barbafina, Arianna,Elisei, Fausto

experimental part, p. 2188 - 2195 (2011/09/30)

The crown thioether 9-[4-(4,7,10,13-tetrathia-1-azacyclopentadecyl]phenyl- N-methylacridinium perchlorate (TCMA) was synthesized and characterized with the aim to verify its ability to interact selectively with metal ions and substantiate the possibility to detect easily the presence of heavy metals in fluid samples. The spectroscopic properties of TCMA, alone and in the presence of metal ions, were therefore studied in polar solvents (MeCN and H 2O); in particular, steady-state UV-Vis spectrophotometric and fluorimetric techniques were used together with transient absorption spectroscopy with fs time resolution to investigate the spectral and dynamic properties of the lowest excited singlet state of TCMA and of TCMA/metal ion complexes. The absorption in the Vis region is characterized by a charge-transfer nature with the methylacridinium moiety acting as the electron-acceptor and the anilic group as the electron-donor. No emission from the S1 was detected both in MeCN and H2O, while a small S2 → S0 fluorescence emission (λmax = 485 nm and F = 0.0011) was detected in water. Time-resolved measurements with fs resolution of TCMA in MeCN have shown that the relaxed S1 state is reached ~0.6 ps after the laser pulse, while the S1 → S0 time constant is 3.7 ps. Among the investigated metal ions, only Fe3+ (in MeCN) and Hg2+ (in MeCN and H2O) were able to form stable complexes (association constant, Kass = 1-11 × 104 M-1) with TCMA. The S1 state of the TCMA/Mn+ complexes emits with low quantum yield (F = 0.0023-0.014) and decays with time constants much longer than TCMA itself, at least in the case of TCMA/Hg2+ in MeCN. This study showed that TCMA is a good candidate for colorimetric/ fluorimetric sensing of Hg2+ in aqueous media owing to its high selectivity towards metal ions. the Owner Societies.

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