((R)-1-allyl-5-(3,4-dimethoxyphenyl)-2-methoxycyclohexa-2,5-dienyl)((S)-2-(methoxymethyl)pyrrolidin-1-yl)methanone

Base Information

Chemical Name:((R)-1-allyl-5-(3,4-dimethoxyphenyl)-2-methoxycyclohexa-2,5-dienyl)((S)-2-(methoxymethyl)pyrrolidin-1-yl)methanone
CAS No.:911847-24-0
Molecular Formula:C₂₅H₃₃NO₅
Molecular Weight:427.541
Hs Code.:

Synonyms:((R)-1-allyl-5-(3,4-dimethoxyphenyl)-2-methoxycyclohexa-2,5-dienyl)((S)-2-(methoxymethyl)pyrrolidin-1-yl)methanone

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Chemical Property of ((R)-1-allyl-5-(3,4-dimethoxyphenyl)-2-methoxycyclohexa-2,5-dienyl)((S)-2-(methoxymethyl)pyrrolidin-1-yl)methanone

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Technology Process of ((R)-1-allyl-5-(3,4-dimethoxyphenyl)-2-methoxycyclohexa-2,5-dienyl)((S)-2-(methoxymethyl)pyrrolidin-1-yl)methanone

There total 1 articles about ((R)-1-allyl-5-(3,4-dimethoxyphenyl)-2-methoxycyclohexa-2,5-dienyl)((S)-2-(methoxymethyl)pyrrolidin-1-yl)methanone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 911847-22-8
(S)-(2-(methoxymethyl)pyrrolidin-1-yl)(3',4,4'-trimethoxybiphenyl-3-yl)methanone

: 106-95-6
allyl bromide

: 911847-24-0
((R)-1-allyl-5-(3,4-dimethoxyphenyl)-2-methoxycyclohexa-2,5-dienyl)((S)-2-(methoxymethyl)pyrrolidin-1-yl)methanone

Guidance literature:: (S)-(2-(methoxymethyl)pyrrolidin-1-yl)(3',4,4'-trimethoxybiphenyl-3-yl)methanone; With ammonia; sodium; In tetrahydrofuran; tert-butyl alcohol; at -78 ℃;

allyl bromide; In tetrahydrofuran; tert-butyl alcohol; at -78 - 20 ℃;
DOI:10.1021/ol0615228

Reference yield: 95.0%

: 911847-24-0
((R)-1-allyl-5-(3,4-dimethoxyphenyl)-2-methoxycyclohexa-2,5-dienyl)((S)-2-(methoxymethyl)pyrrolidin-1-yl)methanone

: 911847-26-2
(R)-2-allyl-4-(3,4-dimethoxyphenyl)-2-((S)-2-(methoxymethyl)pyrrolidin-1-carbonyl)cyclohex-3-en-1-one

Guidance literature:: With hydrogenchloride; In methanol; at 20 ℃; for 15h;
DOI:10.1021/ol0615228

Reference yield:

: 911847-24-0
((R)-1-allyl-5-(3,4-dimethoxyphenyl)-2-methoxycyclohexa-2,5-dienyl)((S)-2-(methoxymethyl)pyrrolidin-1-yl)methanone

: 468-53-1
(3aR,7aR)-3a-(3,4-Dimethoxyphenyl)-1-methylhexahydro-1H-indol-6(2H)-one

Guidance literature:: Multi-step reaction with 7 steps

1.1: 95 percent / HCl / methanol / 15 h / 20 °C

2.1: 80 percent / 1,2-dichloro-benzene / 10 h / Heating

3.1: O₃; Sudan III / methanol / 0.03 h / -78 °C

3.2: dimethyl sulfide / methanol / 7 h / 20 °C

4.1: triethylamine / 1,2-dichloro-ethane / 0.08 h / 20 °C

5.1: 190 mg / NaBH₃CN / 1,2-dichloro-ethane / 6 h / 20 °C

6.1: 60 percent / ethanol / 6 h / Heating

7.1: 75 percent / Mo(CO)6 / acetonitrile; H₂O / 12 h / Heating

With hydrogenchloride; hexacarbonyl molybdenum; oil scarlet; sodium cyanoborohydride; ozone; triethylamine; In methanol; ethanol; water; 1,2-dichloro-ethane; 1,2-dichloro-benzene; acetonitrile; 2.1: Cope rearrangement;
DOI:10.1021/ol0615228