(E)-2-acetoxy-6-(2-tert-butyldimethylsilyloxymethylphenyl)-3-methylhex-3-ene

Base Information

Chemical Name:(E)-2-acetoxy-6-(2-tert-butyldimethylsilyloxymethylphenyl)-3-methylhex-3-ene
CAS No.:147377-88-6
Molecular Formula:C₂₂H₃₆O₃Si
Molecular Weight:376.612
Hs Code.:

Synonyms:(E)-2-acetoxy-6-(2-tert-butyldimethylsilyloxymethylphenyl)-3-methylhex-3-ene

Suppliers and Price of (E)-2-acetoxy-6-(2-tert-butyldimethylsilyloxymethylphenyl)-3-methylhex-3-ene

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (E)-2-acetoxy-6-(2-tert-butyldimethylsilyloxymethylphenyl)-3-methylhex-3-ene

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Technology Process of (E)-2-acetoxy-6-(2-tert-butyldimethylsilyloxymethylphenyl)-3-methylhex-3-ene

There total 9 articles about (E)-2-acetoxy-6-(2-tert-butyldimethylsilyloxymethylphenyl)-3-methylhex-3-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 108-24-7
acetic anhydride

: 147377-90-0
(E)-5-(2-tert-butyldimethylsilyloxymethylphenyl)-1,2-dimethylpent-2-en-1-ol

: 147377-88-6
(E)-2-acetoxy-6-(2-tert-butyldimethylsilyloxymethylphenyl)-3-methylhex-3-ene

Guidance literature:: With pyridine; for 1h; Ambient temperature;

Reference yield:

: 87-41-2
2-benzofuran-1(3H)-one

: 147377-88-6
(E)-2-acetoxy-6-(2-tert-butyldimethylsilyloxymethylphenyl)-3-methylhex-3-ene

Guidance literature:: Multi-step reaction with 9 steps

1: 1.) DIBAH / 1.) toluene, -78 deg C, 1.5 h, 2.) toluene, benzene, 70 deg C, 2 h

2: 94 percent / imidazole, 4-dimethylaminopyridine / CH₂Cl₂ / 2.5 h / Ambient temperature

3: H₂ / 10percent Pd/C / ethanol / 11 h / Ambient temperature

4: DIBAH / CH₂Cl₂; hexane; 1,2-dimethoxy-ethane / 0.25 h / -78 °C

5: 87 percent / benzene / 1 h / Heating

6: 97 percent / DIBAH / toluene; hexane / 0.33 h / -78 °C

7: 96 percent / pyridinium dichromate / CH₂Cl₂ / 2 h / Ambient temperature

8: 82 percent / diethyl ether; tetrahydrofuran / 2.5 h / Ambient temperature

9: 95 percent / pyridine / 1 h / Ambient temperature

With pyridine; 1H-imidazole; dmap; dipyridinium dichromate; hydrogen; diisobutylaluminium hydride; palladium on activated charcoal; In tetrahydrofuran; 1,2-dimethoxyethane; diethyl ether; ethanol; hexane; dichloromethane; toluene; benzene;

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 147377-88-6
(E)-2-acetoxy-6-(2-tert-butyldimethylsilyloxymethylphenyl)-3-methylhex-3-ene

Guidance literature:: Multi-step reaction with 8 steps

1: 94 percent / imidazole, 4-dimethylaminopyridine / CH₂Cl₂ / 2.5 h / Ambient temperature

2: H₂ / 10percent Pd/C / ethanol / 11 h / Ambient temperature

3: DIBAH / CH₂Cl₂; hexane; 1,2-dimethoxy-ethane / 0.25 h / -78 °C

4: 87 percent / benzene / 1 h / Heating

5: 97 percent / DIBAH / toluene; hexane / 0.33 h / -78 °C

6: 96 percent / pyridinium dichromate / CH₂Cl₂ / 2 h / Ambient temperature

7: 82 percent / diethyl ether; tetrahydrofuran / 2.5 h / Ambient temperature

8: 95 percent / pyridine / 1 h / Ambient temperature

With pyridine; 1H-imidazole; dmap; dipyridinium dichromate; hydrogen; diisobutylaluminium hydride; palladium on activated charcoal; In tetrahydrofuran; 1,2-dimethoxyethane; diethyl ether; ethanol; hexane; dichloromethane; toluene; benzene;