1-(4'-methylphenyl)-2,3,4,5-tetramethylcyclopentadienyl titanium trichloride

Base Information

Chemical Name:1-(4'-methylphenyl)-2,3,4,5-tetramethylcyclopentadienyl titanium trichloride
CAS No.:166033-71-2
Molecular Formula:C₁₆H₁₉Cl₃Ti
Molecular Weight:365.566
Hs Code.:

Synonyms:1-(4'-methylphenyl)-2,3,4,5-tetramethylcyclopentadienyl titanium trichloride

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Chemical Property of 1-(4'-methylphenyl)-2,3,4,5-tetramethylcyclopentadienyl titanium trichloride

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Technology Process of 1-(4'-methylphenyl)-2,3,4,5-tetramethylcyclopentadienyl titanium trichloride

There total 2 articles about 1-(4'-methylphenyl)-2,3,4,5-tetramethylcyclopentadienyl titanium trichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 166033-74-5
C₅(C₆H₄CH₃)(CH₃)4(Si(CH₃)3)

: 7550-45-0
titanium tetrachloride

: 166033-71-2
1-(4'-methylphenyl)-2,3,4,5-tetramethylcyclopentadienyl titanium trichloride

Guidance literature:: In toluene; under Ar atm. using Schlenk techniques; recrystd. from toluene/pentane;
DOI:10.1021/om0109197

Reference yield: 76.0%

: 1-(4'-methylphenyl)-2,3,4,5-tetramethylcyclopentadiene

: 7550-45-0
titanium tetrachloride

: 166033-71-2
1-(4'-methylphenyl)-2,3,4,5-tetramethylcyclopentadienyl titanium trichloride

Guidance literature:: With CH₃CH₂CH₂CH₂Li; (CH₃)3SiCl; In toluene; (Ar); addn. of soln. of BuLi to cyclopentadiene deriv. in THF at -78°C, keeping at room temp. for 4 h, addn. of Me3SiCl in THF at -15°C, stirring for 2 h at room temp., evapn., extn. (toluene), addn. ofTiCl4 in toluene at -78°C; filtration, evapn., recrystn. (CH2Cl2/hexane (1:3)), elem. anal.;
DOI:10.1039/b921617k

Reference yield: 82.0%

: 102-71-6,64114-46-1
triethanolamine

: 166033-71-2
1-(4'-methylphenyl)-2,3,4,5-tetramethylcyclopentadienyl titanium trichloride

: 413601-45-3
(C₅(C₆H₄CH₃)(CH₃)4)Ti(N(CH₂CH₂O)3)

Guidance literature:: With N(C₂H₅)3; In dichloromethane; under Ar atm. using Schlenk techniques; soln. of Ti complex in CH2Cl2 added to stirred soln. of N(CH2CH2OH)3 and NEt3 in CH2Cl2 at -78°C;mixt. warmed to room temp.; stirred for 12 h; solvent removed (vac.); redissolved (toluene); filtered; solvent removed; elem. anal.;
DOI:10.1021/om0109197