tert-butyl{[3-isobutyl-2,6-bis(methoxymethoxy)benzyl]oxy}dimethylsilane

Base Information

Chemical Name:tert-butyl{[3-isobutyl-2,6-bis(methoxymethoxy)benzyl]oxy}dimethylsilane
CAS No.:912654-49-0
Molecular Formula:C₂₁H₃₈O₅Si
Molecular Weight:398.615
Hs Code.:

Synonyms:tert-butyl{[3-isobutyl-2,6-bis(methoxymethoxy)benzyl]oxy}dimethylsilane

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Chemical Property of tert-butyl{[3-isobutyl-2,6-bis(methoxymethoxy)benzyl]oxy}dimethylsilane

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Technology Process of tert-butyl{[3-isobutyl-2,6-bis(methoxymethoxy)benzyl]oxy}dimethylsilane

There total 6 articles about tert-butyl{[3-isobutyl-2,6-bis(methoxymethoxy)benzyl]oxy}dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

: 912654-48-9
[3-isobutyl-2,6-bis(methoxymethoxy)phenyl]methanol

: 18162-48-6
tert-butyldimethylsilyl chloride

: 912654-49-0
tert-butyl{[3-isobutyl-2,6-bis(methoxymethoxy)benzyl]oxy}dimethylsilane

Guidance literature:: With 1H-imidazole; In N,N-dimethyl-formamide; at 20 ℃; for 36h;
DOI:10.1021/jo061104g

Reference yield:

: 912654-45-6
2,4-bis(methoxymethoxy)-1-(2-methylprop-1-enyl)benzene

: 912654-49-0
tert-butyl{[3-isobutyl-2,6-bis(methoxymethoxy)benzyl]oxy}dimethylsilane

Guidance literature:: Multi-step reaction with 4 steps

1.1: 93 percent / H₂ / Pd/C / ethanol / 24 h / 3102.89 Torr

2.1: n-BuLi; TMEDA / diethyl ether; hexane / 2 h / 0 °C

2.2: 86 percent / diethyl ether; hexane / 3 h / 20 °C

3.1: 95 percent / NaBH₄ / tetrahydrofuran / 1.5 h / 20 °C

4.1: 85 percent / imidazole / dimethylformamide / 36 h / 20 °C

With 1H-imidazole; sodium tetrahydroborate; n-butyllithium; N,N,N,N,-tetramethylethylenediamine; hydrogen; palladium on activated charcoal; In tetrahydrofuran; diethyl ether; ethanol; hexane; N,N-dimethyl-formamide;
DOI:10.1021/jo061104g

Reference yield:

: 13709-06-3
2,4-bis(methoxymethoxy)benzaldehyde

: 912654-49-0
tert-butyl{[3-isobutyl-2,6-bis(methoxymethoxy)benzyl]oxy}dimethylsilane

Guidance literature:: Multi-step reaction with 5 steps

1.1: 94 percent / tetrahydrofuran; hexane / 4 h / 20 °C

2.1: 93 percent / H₂ / Pd/C / ethanol / 24 h / 3102.89 Torr

3.1: n-BuLi; TMEDA / diethyl ether; hexane / 2 h / 0 °C

3.2: 86 percent / diethyl ether; hexane / 3 h / 20 °C

4.1: 95 percent / NaBH₄ / tetrahydrofuran / 1.5 h / 20 °C

5.1: 85 percent / imidazole / dimethylformamide / 36 h / 20 °C

With 1H-imidazole; sodium tetrahydroborate; n-butyllithium; N,N,N,N,-tetramethylethylenediamine; hydrogen; palladium on activated charcoal; In tetrahydrofuran; diethyl ether; ethanol; hexane; N,N-dimethyl-formamide; 1.1: Wittig reaction;
DOI:10.1021/jo061104g