tris(2,6-di-tert-butyl-4-methylphenolato)samarium(III)(tetrahydrofuran) - tetrahydrofuran (1/1)

Base Information

Chemical Name:tris(2,6-di-tert-butyl-4-methylphenolato)samarium(III)(tetrahydrofuran) - tetrahydrofuran (1/1)
CAS No.:162378-88-3
Molecular Formula:C₄H₈O*C₄₉H₇₇O₄Sm
Molecular Weight:952.615
Hs Code.:

Synonyms:tris(2,6-di-tert-butyl-4-methylphenolato)samarium(III)(tetrahydrofuran) - tetrahydrofuran (1/1)

Suppliers and Price of tris(2,6-di-tert-butyl-4-methylphenolato)samarium(III)(tetrahydrofuran) - tetrahydrofuran (1/1)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of tris(2,6-di-tert-butyl-4-methylphenolato)samarium(III)(tetrahydrofuran) - tetrahydrofuran (1/1)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of tris(2,6-di-tert-butyl-4-methylphenolato)samarium(III)(tetrahydrofuran) - tetrahydrofuran (1/1)

There total 2 articles about tris(2,6-di-tert-butyl-4-methylphenolato)samarium(III)(tetrahydrofuran) - tetrahydrofuran (1/1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: 7440-19-9
samarium

: 936842-48-7
(2,6-di-tert-butyl-4-methylphenolato)trimethyltin(IV)

: 162378-88-3
tris(2,6-di-tert-butyl-4-methylphenolato)samarium(III)(tetrahydrofuran) - tetrahydrofuran (1/1)

: 661-69-8
hexamethyldistannane

Guidance literature:: With Hg; In tetrahydrofuran; Sonication; (N2), THF added to mixt. of Sm metal, Sn complex and 2 drops of Hg, sonicated at room temp. for 5 d; filtered, evapd.(vac.), washed (hexane), elem. anal.;
DOI:10.1002/ejic.200600045

Reference yield: 43.1%

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: 16654-89-0
sodium 2,6-di-tert-butyl-4-methylphenoxide

: 10361-82-7
samarium(III) chloride

: 162378-88-3
tris(2,6-di-tert-butyl-4-methylphenolato)samarium(III)(tetrahydrofuran) - tetrahydrofuran (1/1)

Guidance literature:: In tetrahydrofuran; byproducts: NaCl; (Ar); stirring (25°C, 48 h); decanting, solvent redn. (vac.), adding hexane, crystn. on cooling to -5°C; elem. anal.;
DOI:10.1016/0277-5387(94)00251-9