methyl 2-((4S,6S)-4-(benzyloxy)-6-(methoxymethoxy)heptyl)-4,6-dimethoxybenzoate

Base Information

Chemical Name:methyl 2-((4S,6S)-4-(benzyloxy)-6-(methoxymethoxy)heptyl)-4,6-dimethoxybenzoate
CAS No.:1413626-94-4
Molecular Formula:C₂₆H₃₆O₇
Molecular Weight:460.568
Hs Code.:

Synonyms:methyl 2-((4S,6S)-4-(benzyloxy)-6-(methoxymethoxy)heptyl)-4,6-dimethoxybenzoate

Suppliers and Price of methyl 2-((4S,6S)-4-(benzyloxy)-6-(methoxymethoxy)heptyl)-4,6-dimethoxybenzoate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of methyl 2-((4S,6S)-4-(benzyloxy)-6-(methoxymethoxy)heptyl)-4,6-dimethoxybenzoate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of methyl 2-((4S,6S)-4-(benzyloxy)-6-(methoxymethoxy)heptyl)-4,6-dimethoxybenzoate

There total 7 articles about methyl 2-((4S,6S)-4-(benzyloxy)-6-(methoxymethoxy)heptyl)-4,6-dimethoxybenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 37567-78-5
1,5-dimethoxy-1,4-cyclohexadiene

: 1413626-90-0
C₂₀H₂₈O₅

: 1413626-94-4
methyl 2-((4S,6S)-4-(benzyloxy)-6-(methoxymethoxy)heptyl)-4,6-dimethoxybenzoate

Guidance literature:: With N,N-dimethyl-aniline; at 180 ℃; for 48h; Sealed tube;
DOI:10.1016/j.tetlet.2012.09.032

Reference yield:

: 1413626-82-0
C₂₃H₃₂O₆S

: 1413626-94-4
methyl 2-((4S,6S)-4-(benzyloxy)-6-(methoxymethoxy)heptyl)-4,6-dimethoxybenzoate

Guidance literature:: Multi-step reaction with 3 steps

1: dimethyl sulfoxide / 6 h / 20 °C

2: n-butyllithium / tetrahydrofuran / 1 h / -78 °C

3: N,N-dimethyl-aniline / 48 h / 180 °C / Sealed tube

With n-butyllithium; N,N-dimethyl-aniline; In tetrahydrofuran; dimethyl sulfoxide; 3: |Diels-Alder Cycloaddition;
DOI:10.1016/j.tetlet.2012.09.032

Reference yield:

: C₁₆H₂₁NO₆

: 1413626-94-4
methyl 2-((4S,6S)-4-(benzyloxy)-6-(methoxymethoxy)heptyl)-4,6-dimethoxybenzoate

Guidance literature:: Multi-step reaction with 7 steps

1.1: potassium carbonate; methanol / tetrahydrofuran / 1 h / 20 °C

2.1: sodium hydride / tetrahydrofuran / 8 h / 20 °C

3.1: dimethylsulfide borane complex / tetrahydrofuran / 8 h / 0 °C

3.2: 4 h / 20 °C

4.1: triethylamine / dichloromethane / 3 h / 0 - 20 °C

5.1: dimethyl sulfoxide / 6 h / 20 °C

6.1: n-butyllithium / tetrahydrofuran / 1 h / -78 °C

7.1: N,N-dimethyl-aniline / 48 h / 180 °C / Sealed tube

With methanol; n-butyllithium; dimethylsulfide borane complex; sodium hydride; potassium carbonate; N,N-dimethyl-aniline; triethylamine; In tetrahydrofuran; dichloromethane; dimethyl sulfoxide; 7.1: |Diels-Alder Cycloaddition;
DOI:10.1016/j.tetlet.2012.09.032