5,7,12,13b,13c,14-Hexahydro-1,4,8,11-tetramethoxy-13b,13c-diphenyl-6H,13H-5a,6a,12a,13a-tetraazabenz<5,6>azuleno<2,1,8-ija>benzazulene-6,13-dione

Base Information

• Chemical Name: 5,7,12,13b,13c,14-Hexahydro-1,4,8,11-tetramethoxy-13b,13c-diphenyl-6H,13H-5a,6a,12a,13a-tetraazabenz<5,6>azuleno<2,1,8-ija>benzazulene-6,13-dione
• CAS No.: 106319-03-3
• Molecular Formula: C₃₆H₃₄N₄O₆
• Molecular Weight: 618.689
• Mol file: 106319-03-3.mol

Synonyms:5,7,12,13b,13c,14-Hexahydro-1,4,8,11-tetramethoxy-13b,13c-diphenyl-6H,13H-5a,6a,12a,13a-tetraazabenz<5,6>azuleno<2,1,8-ija>benzazulene-6,13-dione

Chemical Property of 5,7,12,13b,13c,14-Hexahydro-1,4,8,11-tetramethoxy-13b,13c-diphenyl-6H,13H-5a,6a,12a,13a-tetraazabenz<5,6>azuleno<2,1,8-ija>benzazulene-6,13-dione

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,7,12,13b,13c,14-Hexahydro-1,4,8,11-tetramethoxy-13b,13c-diphenyl-6H,13H-5a,6a,12a,13a-tetraazabenz<5,6>azuleno<2,1,8-ija>benzazulene-6,13-dione

There total 10 articles about 5,7,12,13b,13c,14-Hexahydro-1,4,8,11-tetramethoxy-13b,13c-diphenyl-6H,13H-5a,6a,12a,13a-tetraazabenz<5,6>azuleno<2,1,8-ija>benzazulene-6,13-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

1,6:3,4-bis(2-oxapropylene)tetrahydro-3a,6a-diphenylimidazo[4,5-d]imidazole-2,5(1H,3H)-dione (121619-22-5) + 1,4-dimethoxybezene (150-78-7) → 5,7,12,13b,13c,14-Hexahydro-1,4,8,11-tetramethoxy-13b,13c-diphenyl-6H,13H-5a,6a,12a,13a-tetraazabenz<5,6>azuleno<2,1,8-ija>benzazulene-6,13-dione (106319-03-3)

Guidance literature:

With acetic anhydride; trifluoroacetic acid; at 95 ℃; for 0.5h; Heating;

DOI:10.1002/recl.19931121207

Reference yield: 95.0%

1,3,4,6-Tetrakis(chloromethyl)tetrahydro-3a,6a-diphenylimidazo<4,5-d>imidazole-2,5(1H,3H)-dione (146443-42-7) + 1,4-dimethoxybezene (150-78-7) → 5,7,12,13b,13c,14-Hexahydro-1,4,8,11-tetramethoxy-13b,13c-diphenyl-6H,13H-5a,6a,12a,13a-tetraazabenz<5,6>azuleno<2,1,8-ija>benzazulene-6,13-dione (106319-03-3)

Guidance literature:

With tin(IV) chloride;

DOI:10.1021/jo00010a001

Reference yield: 71.0%

formaldehyd (50-00-0,30525-89-4,61233-19-0) + 3a,6a-diphenylglycoluril (5157-15-3) + 1,4-dimethoxybezene (150-78-7) → 5,7,12,13b,13c,14-Hexahydro-1,4,8,11-tetramethoxy-13b,13c-diphenyl-6H,13H-5a,6a,12a,13a-tetraazabenz<5,6>azuleno<2,1,8-ija>benzazulene-6,13-dione (106319-03-3)

Guidance literature:

formaldehyd; 3a,6a-diphenylglycoluril; With methanesulfonic acid; In 1,2-dichloro-ethane; for 3h; Reflux;

1,4-dimethoxybezene; In 1,2-dichloro-ethane; for 20h; Reflux;

DOI:10.1007/s00706-007-0850-8

upstream raw materials:

1,6:3,4-bis(2-oxapropylene)tetrahydro-3a,6a-diphenylimidazo[4,5-d]imidazole-2,5(1H,3H)-dione

1,4-dimethoxybezene

1,3,4,6-Tetrakis(chloromethyl)tetrahydro-3a,6a-diphenylimidazo<4,5-d>imidazole-2,5(1H,3H)-dione

1,3,4,6-tatrakis(hydroxymethyl)tetrahydro-3a,6a-diphenylimidazo<4,5-d>imidazole-2,5(1H,3H)-dione

Downstream raw materials:

(C₆H₄OHCHN)4(C₆(OCH₃)2)2(CH₂NCONCH₂)2(CC₆H₅)2

5,7,12,13b,13c,14-hexahydro-1,4,8,11-tetramethoxy-2,3,9,10-tetraamino-13b,13c-diphenyl-6H,13H-5a,6a,12a,13a-tetraazabenz[5,6]azuleno[2,1,8-ija]benz[f]azulene-6,13-dione

5,7,12,13b,13c,14-hexahydro-1,4,8,11-tetramethoxy-2,3,9,10-tetranitro-13b,13c-diphenyl-6H,13H-5a,6a,12a,13a-tetraazabenz[5,6]azuleno[2,1,8-ija]benz[f]azulene-6,13-dione