5,7,12,13b,13c,14-hexahydro-1,4,8,11-tetramethoxy-2,3,9,10-tetraamino-13b,13c-diphenyl-6H,13H-5a,6a,12a,13a-tetraazabenz[5,6]azuleno[2,1,8-ija]benz[f]azulene-6,13-dione

Base Information

• Chemical Name: 5,7,12,13b,13c,14-hexahydro-1,4,8,11-tetramethoxy-2,3,9,10-tetraamino-13b,13c-diphenyl-6H,13H-5a,6a,12a,13a-tetraazabenz[5,6]azuleno[2,1,8-ija]benz[f]azulene-6,13-dione
• CAS No.: 188427-80-7
• Molecular Formula: C₃₆H₃₈N₈O₆
• Molecular Weight: 678.748
• Mol file: 188427-80-7.mol

Synonyms:5,7,12,13b,13c,14-hexahydro-1,4,8,11-tetramethoxy-2,3,9,10-tetraamino-13b,13c-diphenyl-6H,13H-5a,6a,12a,13a-tetraazabenz[5,6]azuleno[2,1,8-ija]benz[f]azulene-6,13-dione

Chemical Property of 5,7,12,13b,13c,14-hexahydro-1,4,8,11-tetramethoxy-2,3,9,10-tetraamino-13b,13c-diphenyl-6H,13H-5a,6a,12a,13a-tetraazabenz[5,6]azuleno[2,1,8-ija]benz[f]azulene-6,13-dione

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 5,7,12,13b,13c,14-hexahydro-1,4,8,11-tetramethoxy-2,3,9,10-tetraamino-13b,13c-diphenyl-6H,13H-5a,6a,12a,13a-tetraazabenz[5,6]azuleno[2,1,8-ija]benz[f]azulene-6,13-dione

There total 2 articles about 5,7,12,13b,13c,14-hexahydro-1,4,8,11-tetramethoxy-2,3,9,10-tetraamino-13b,13c-diphenyl-6H,13H-5a,6a,12a,13a-tetraazabenz[5,6]azuleno[2,1,8-ija]benz[f]azulene-6,13-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

5,7,12,13b,13c,14-hexahydro-1,4,8,11-tetramethoxy-2,3,9,10-tetranitro-13b,13c-diphenyl-6H,13H-5a,6a,12a,13a-tetraazabenz[5,6]azuleno[2,1,8-ija]benz[f]azulene-6,13-dione (188427-79-4) → 5,7,12,13b,13c,14-hexahydro-1,4,8,11-tetramethoxy-2,3,9,10-tetraamino-13b,13c-diphenyl-6H,13H-5a,6a,12a,13a-tetraazabenz[5,6]azuleno[2,1,8-ija]benz[f]azulene-6,13-dione (188427-80-7)

Guidance literature:

With triethylammonium formate; palladium on activated charcoal; In tetrahydrofuran; methanol;

DOI:10.1002/recl.19931120616

Reference yield:

5,7,12,13b,13c,14-Hexahydro-1,4,8,11-tetramethoxy-13b,13c-diphenyl-6H,13H-5a,6a,12a,13a-tetraazabenz<5,6>azuleno<2,1,8-ija>benzazulene-6,13-dione (106319-03-3) → 5,7,12,13b,13c,14-hexahydro-1,4,8,11-tetramethoxy-2,3,9,10-tetraamino-13b,13c-diphenyl-6H,13H-5a,6a,12a,13a-tetraazabenz[5,6]azuleno[2,1,8-ija]benz[f]azulene-6,13-dione (188427-80-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 89 percent / 65percent aq. nitric acid, acetic anhydride

2: triethylammonium formate / Pd/C / tetrahydrofuran; methanol

With nitric acid; acetic anhydride; triethylammonium formate; palladium on activated charcoal; In tetrahydrofuran; methanol;

DOI:10.1002/recl.19931120616

Reference yield:

benzil (134-81-6) + 5,7,12,13b,13c,14-hexahydro-1,4,8,11-tetramethoxy-2,3,9,10-tetraamino-13b,13c-diphenyl-6H,13H-5a,6a,12a,13a-tetraazabenz[5,6]azuleno[2,1,8-ija]benz[f]azulene-6,13-dione (188427-80-7) → 5,7,12,13b,13c,14-hexahydro-1,4,8,11-tetramethoxy-13b,13c-diphenyl-6H,13H-5a,6a,12a,13a-tetraaza(3,6-diaza-4,5-diphenylbenz[1,2-d])benz[5,6]azuleno[2,1,8-ija](3,6-diaza-4,5-diphenylbenz[1,2-d])benz[f]azulene-6,13-dione

Guidance literature:

With molecular sieve; In tetrahydrofuran; methanol; for 16h; Heating;

DOI:10.1039/b715208f

upstream raw materials:

5,7,12,13b,13c,14-hexahydro-1,4,8,11-tetramethoxy-2,3,9,10-tetranitro-13b,13c-diphenyl-6H,13H-5a,6a,12a,13a-tetraazabenz[5,6]azuleno[2,1,8-ija]benz[f]azulene-6,13-dione

5,7,12,13b,13c,14-Hexahydro-1,4,8,11-tetramethoxy-13b,13c-diphenyl-6H,13H-5a,6a,12a,13a-tetraazabenz<5,6>azuleno<2,1,8-ija>benzazulene-6,13-dione

Downstream raw materials:

(C₆H₄OHCHN)4(C₆(OCH₃)2)2(CH₂NCONCH₂)2(CC₆H₅)2