{Re(CCMe₂Ph){O-t-Bu}2I₂

Base Information

• Chemical Name: {Re(CCMe₂Ph){O-t-Bu}2I₂
• CAS No.: 133421-16-6
• Molecular Formula: C₁₈H₂₉I₂O₂Re
• Molecular Weight: 717.443
• Mol file: 133421-16-6.mol

Synonyms:{Re(CCMe₂Ph){O-t-Bu}2I₂

Chemical Property of {Re(CCMe₂Ph){O-t-Bu}2I₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {Re(CCMe₂Ph){O-t-Bu}2I₂

There total 3 articles about {Re(CCMe₂Ph){O-t-Bu}2I₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

{Re(CCMe2Ph){O-t-Bu}2}2 (182417-35-2,133421-14-4) + iodine (7553-56-2,12190-71-5,8031-47-8) → {Re(CCMe2Ph){O-t-Bu}2I2 (133421-16-6)

Guidance literature:

In diethyl ether; N2-atmosphere; addn. of slight excess I2 to Re-complex at -40°C, stirring at room temp. for 45 min; solvent removal (vac.), extn. into pentane, filtration, cooling (crystn.), collection, washing (cold pentane); elem. anal.;

DOI:10.1016/0022-328X(96)06264-X

Reference yield:

{Re(CCMe2Ph){O-t-Bu}2}2 (182417-35-2,133421-14-4) → {Re(CCMe2Ph){O-t-Bu}2I2 (133421-16-6)

Guidance literature:

With iodine; In diethyl ether; -40°C;

DOI:10.1021/ja00009a068

Reference yield:

Re(CC(CH3)2C6H5)(CHC(CH3)2C6H5)(OC(CH3)3)2 (133421-15-5,139973-36-7,139973-37-8) → {Re(CCMe2Ph){O-t-Bu}2I2 (133421-16-6)

Guidance literature:

Multi-step reaction with 2 steps

1: ethyl vinyl ether / pentane

2: diethyl ether

With ethyl vinyl ether; In diethyl ether; pentane;

DOI:10.1016/0022-328X(96)06264-X

upstream raw materials:

{Re(CCMe₂Ph){O-t-Bu}2}2

iodine

Re(CC(CH₃)2C₆H₅)(CHC(CH₃)2C₆H₅)(OC(CH₃)3)2