N(C₂H₅)4⁽¹⁺⁾*Mn(CH₃C₅H₄)(CO)2(Si(C₆H₅)3)^(1-) = [N(C₂H₅)4][Mn(CH₃C₅H₄)(CO)2(Si(C₆H₅)3)]

Base Information

• Chemical Name: N(C₂H₅)4⁽¹⁺⁾*Mn(CH₃C₅H₄)(CO)2(Si(C₆H₅)3)^(1-) = [N(C₂H₅)4][Mn(CH₃C₅H₄)(CO)2(Si(C₆H₅)3)]
• CAS No.: 68844-76-8
• Molecular Formula: C₈H₂₀N*C₂₆H₂₂MnO₂Si
• Molecular Weight: 579.736
• Mol file: 68844-76-8.mol

Synonyms:N(C₂H₅)4⁽¹⁺⁾*Mn(CH₃C₅H₄)(CO)2(Si(C₆H₅)3)^(1-) = [N(C₂H₅)4][Mn(CH₃C₅H₄)(CO)2(Si(C₆H₅)3)]

Chemical Property of N(C₂H₅)4⁽¹⁺⁾*Mn(CH₃C₅H₄)(CO)2(Si(C₆H₅)3)^(1-) = [N(C₂H₅)4][Mn(CH₃C₅H₄)(CO)2(Si(C₆H₅)3)]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of N(C₂H₅)4⁽¹⁺⁾*Mn(CH₃C₅H₄)(CO)2(Si(C₆H₅)3)^(1-) = [N(C₂H₅)4][Mn(CH₃C₅H₄)(CO)2(Si(C₆H₅)3)]

There total 1 articles about N(C₂H₅)4⁽¹⁺⁾*Mn(CH₃C₅H₄)(CO)2(Si(C₆H₅)3)^(1-) = [N(C₂H₅)4][Mn(CH₃C₅H₄)(CO)2(Si(C₆H₅)3)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

η5-CH3C5H4(CO)2(CH3)((C6H5)3Si)Mn + triphenyl germyllithium (3839-32-5) + tetraethylammonium chloride (56-34-8) → N(C2H5)4(1+)*Mn(CH3C5H4)(CO)2(Si(C6H5)3)(1-) = [N(C2H5)4][Mn(CH3C5H4)(CO)2(Si(C6H5)3)] (68844-76-8) + methyltriphenylgermane (2817-44-9)

Guidance literature:

In diethyl ether; Mn-complex and Ph3GeLi stirred 1 h in ether at room temp.; solvent pumped off; CH2Cl2 addn.; addn. excess Et4NCl in CH2Cl2; 10 min; filtered; solvent pumped off; residue dissolved in THF; excess Et4NCl filtered; standing at -20°C; mother liquor evapd.; chromd. (silicagel), elution with hexane/benzene;

DOI:10.1021/ic00131a066

Reference yield: 78.0%

N(C2H5)4(1+)*Mn(CH3C5H4)(CO)2(Si(C6H5)3)(1-) = [N(C2H5)4][Mn(CH3C5H4)(CO)2(Si(C6H5)3)] (68844-76-8) + 4-iodobut-1-ene (7766-51-0) → Mn(C5H4CH3)(CO)2(Si(C6H5)3)(CH2CH2CHCH2) (89958-50-9)

Guidance literature:

In tetrahydrofuran; stirring at 4°C for 30 min; filtered; solvent was pumped off; taken up in toluene and pentane; standing at -20°C;; crystd. from hexane; elem. anal.;;

DOI:10.1016/0022-328X(84)80163-1

Reference yield: 75.0%

N(C2H5)4(1+)*Mn(CH3C5H4)(CO)2(Si(C6H5)3)(1-) = [N(C2H5)4][Mn(CH3C5H4)(CO)2(Si(C6H5)3)] (68844-76-8) → η5-CH3C5H4(CO)2(CH3)((C6H5)3Si)Mn

Guidance literature:

With methyl iodide; In tetrahydrofuran; stirring at room temp. for 30 min; filtered; solvent was pumped off; taken up in toluene and pentane; standing at -20°C;; elem. anal.;;

DOI:10.1016/0022-328X(84)80163-1

upstream raw materials:

triphenyl germyllithium

tetraethylammonium chloride

Downstream raw materials:

Mn(C₅H₄CH₃)(CO)2(Si(C₆H₅)3)(CH₂CH₂CHCH₂)