(2E,6E)-9-cyclohexyl-3,7-dimethyl-8-phenylthio-1-(tetrahydro-2-pyranyl)oxy-2,6-nonadiene

Base Information

Chemical Name:(2E,6E)-9-cyclohexyl-3,7-dimethyl-8-phenylthio-1-(tetrahydro-2-pyranyl)oxy-2,6-nonadiene
CAS No.:502763-28-2
Molecular Formula:C₂₈H₄₂O₂S
Molecular Weight:442.706
Hs Code.:

Synonyms:(2E,6E)-9-cyclohexyl-3,7-dimethyl-8-phenylthio-1-(tetrahydro-2-pyranyl)oxy-2,6-nonadiene

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Chemical Property of (2E,6E)-9-cyclohexyl-3,7-dimethyl-8-phenylthio-1-(tetrahydro-2-pyranyl)oxy-2,6-nonadiene

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Technology Process of (2E,6E)-9-cyclohexyl-3,7-dimethyl-8-phenylthio-1-(tetrahydro-2-pyranyl)oxy-2,6-nonadiene

There total 3 articles about (2E,6E)-9-cyclohexyl-3,7-dimethyl-8-phenylthio-1-(tetrahydro-2-pyranyl)oxy-2,6-nonadiene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

: 2550-36-9
Cyclohexylmethyl bromide

: 502763-27-1
(2E,6E)-3,7-dimethyl-8-phenylthio-1-(tetrahydro-2-pyranyl)oxy-2,6-octadiene

: 502763-28-2
(2E,6E)-9-cyclohexyl-3,7-dimethyl-8-phenylthio-1-(tetrahydro-2-pyranyl)oxy-2,6-nonadiene

Guidance literature:: (2E,6E)-3,7-dimethyl-8-phenylthio-1-(tetrahydro-2-pyranyl)oxy-2,6-octadiene; With 1,4-diaza-bicyclo[2.2.2]octane; n-butyllithium; In tetrahydrofuran; at 0 ℃; for 0.5h;

Cyclohexylmethyl bromide; In tetrahydrofuran; at 0 - 20 ℃;
DOI:10.1016/S0040-4020(02)01455-2

Reference yield:

: 66408-80-8,70238-39-0,80444-67-3,143590-48-1,38290-53-8
(2E,6E)-2,6-dimethyl-8-((tetrahydro-2H-pyran-2-yl)oxy)octa-2,6-dien-1-ol

: 502763-28-2
(2E,6E)-9-cyclohexyl-3,7-dimethyl-8-phenylthio-1-(tetrahydro-2-pyranyl)oxy-2,6-nonadiene

Guidance literature:: Multi-step reaction with 2 steps

1.1: 90 percent / (n-C₄H₉)3P; pyridine / 2.5 h / 20 °C

2.1: n-C₄H₉Li; 1,4-diazabicyclo[2.2.2]octane / tetrahydrofuran / 0.5 h / 0 °C

2.2: 51 percent / tetrahydrofuran / 0 - 20 °C

With pyridine; 1,4-diaza-bicyclo[2.2.2]octane; n-butyllithium; tributylphosphine; In tetrahydrofuran;
DOI:10.1016/S0040-4020(02)01455-2

Reference yield:

: 882-33-7
diphenyldisulfane

: 502763-28-2
(2E,6E)-9-cyclohexyl-3,7-dimethyl-8-phenylthio-1-(tetrahydro-2-pyranyl)oxy-2,6-nonadiene

Guidance literature:: Multi-step reaction with 2 steps

1.1: 90 percent / (n-C₄H₉)3P; pyridine / 2.5 h / 20 °C

2.1: n-C₄H₉Li; 1,4-diazabicyclo[2.2.2]octane / tetrahydrofuran / 0.5 h / 0 °C

2.2: 51 percent / tetrahydrofuran / 0 - 20 °C

With pyridine; 1,4-diaza-bicyclo[2.2.2]octane; n-butyllithium; tributylphosphine; In tetrahydrofuran;
DOI:10.1016/S0040-4020(02)01455-2