(2S,3S,4R,6R)-2,4-Dimethyl-6-phenylsulfanyl-3-triethylsilanyloxy-tetrahydro-pyran-4-ol

Base Information

• Chemical Name: (2S,3S,4R,6R)-2,4-Dimethyl-6-phenylsulfanyl-3-triethylsilanyloxy-tetrahydro-pyran-4-ol
• CAS No.: 338387-39-6
• Molecular Formula: C₁₉H₃₂O₃SSi
• Molecular Weight: 368.613
• Mol file: 338387-39-6.mol

Synonyms:(2S,3S,4R,6R)-2,4-Dimethyl-6-phenylsulfanyl-3-triethylsilanyloxy-tetrahydro-pyran-4-ol

Chemical Property of (2S,3S,4R,6R)-2,4-Dimethyl-6-phenylsulfanyl-3-triethylsilanyloxy-tetrahydro-pyran-4-ol

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of (2S,3S,4R,6R)-2,4-Dimethyl-6-phenylsulfanyl-3-triethylsilanyloxy-tetrahydro-pyran-4-ol

There total 1 articles about (2S,3S,4R,6R)-2,4-Dimethyl-6-phenylsulfanyl-3-triethylsilanyloxy-tetrahydro-pyran-4-ol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C13H18O3S + triethylsilyl chloride (994-30-9) → (2S,3S,4R,6S)-2,4-Dimethyl-6-phenylsulfanyl-3-triethylsilanyloxy-tetrahydro-pyran-4-ol (338387-38-5) + (2S,3S,4R,6R)-2,4-Dimethyl-6-phenylsulfanyl-3-triethylsilanyloxy-tetrahydro-pyran-4-ol (338387-39-6)

Guidance literature:

With 1H-imidazole; In N,N-dimethyl-formamide; at 23 ℃; for 1.5h; Title compound not separated from byproducts.;

DOI:10.1021/ja071205b

Reference yield:

(2S,3S,4R,6R)-2,4-Dimethyl-6-phenylsulfanyl-3-triethylsilanyloxy-tetrahydro-pyran-4-ol (338387-39-6) + C63H75ClN2O17Si

Guidance literature:

With 2,6-di-tert-butyl-4-methylpyridine; silver(I) hexafluorophosphate; 4 A molecular sieve; In dichloromethane; at 0 ℃; for 6h;

DOI:10.1002/1521-3773(20010302)40:5<946::AID-ANIE946>3.0.CO;2-G

upstream raw materials:

triethylsilyl chloride