3-methoxy-N-benzoyliminopyridinium ylide

Base Information

• Chemical Name: 3-methoxy-N-benzoyliminopyridinium ylide
• CAS No.: 28460-35-7
• Molecular Formula: C₁₃H₁₂N₂O₂
• Molecular Weight: 228.25
• Mol file: 28460-35-7.mol

Synonyms:3-methoxy-N-benzoyliminopyridinium ylide

Chemical Property of 3-methoxy-N-benzoyliminopyridinium ylide

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of 3-methoxy-N-benzoyliminopyridinium ylide

There total 2 articles about 3-methoxy-N-benzoyliminopyridinium ylide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-(2,4-dinitrophenyl)-3-methoxypyridinium chloride (104642-51-5) + benzoic acid hydrazide (613-94-5) → 3-methoxy-N-benzoyliminopyridinium ylide (28460-35-7)

Guidance literature:

With triethylamine; Yield given. Multistep reaction; 1.) MeOH, RT, overnight, 2.) dioxane, H₂O, reflux, 12 h;

DOI:10.1021/jm00384a018

Reference yield:

→ 3-methoxy-N-benzoyliminopyridinium ylide (28460-35-7)

Guidance literature:

N-Benzoylimino-3-hydroxy-pyridiniumylid (7l), tert-Butylalkohol, Diazomethan, Ae.;

DOI:10.1002/hlca.19780610815

Reference yield: 89.0%

3-methoxy-N-benzoyliminopyridinium ylide (28460-35-7) + C17H32N2O3Si → C30H44N2O5Si

Guidance literature:

With C₈₀H₈₀N₄O₁₆Ru₂; In fluorobenzene; at 0 ℃; enantioselective reaction; Molecular sieve;

DOI:10.1002/anie.201305539

upstream raw materials:

1-(2,4-dinitrophenyl)-3-methoxypyridinium chloride

benzoic acid hydrazide

Downstream raw materials:

N-(5-Methoxy-3,6-dihydro-2H-pyridin-1-yl)-benzamide

Refernces