(E,E,7S)-methyl-8-<(2R,6S)-6-<(2S,3R,4S,6R,7R,8R,9S,10S,11S)-2-methoxy-3,7,9,11-tetramethyl-8,10-dihydroxy-4,6-((R)-para-methoxybenzylidenedioxy)-13-((2S,4R,6S)-2-methyl-4-methoxytetrahydropyran-6-yl)-tridecan-1-yl>-5,6-dihydro-2H-pyran-2-yl>-7-tert-...

Base Information

• Chemical Name: (E,E,7S)-methyl-8-<(2R,6S)-6-<(2S,3R,4S,6R,7R,8R,9S,10S,11S)-2-methoxy-3,7,9,11-tetramethyl-8,10-dihydroxy-4,6-((R)-para-methoxybenzylidenedioxy)-13-((2S,4R,6S)-2-methyl-4-methoxytetrahydropyran-6-yl)-tridecan-1-yl>-5,6-dihydro-2H-pyran-2-yl>-7-tert-...
• CAS No.: 158751-34-9
• Molecular Formula: C₅₄H₉₀O₁₂Si
• Molecular Weight: 959.387
• Mol file: 158751-34-9.mol

Synonyms:(E,E,7S)-methyl-8-<(2R,6S)-6-<(2S,3R,4S,6R,7R,8R,9S,10S,11S)-2-methoxy-3,7,9,11-tetramethyl-8,10-dihydroxy-4,6-((R)-para-methoxybenzylidenedioxy)-13-((2S,4R,6S)-2-methyl-4-methoxytetrahydropyran-6-yl)-tridecan-1-yl>-5,6-dihydro-2H-pyran-2-yl>-7-tert-...

Chemical Property of (E,E,7S)-methyl-8-<(2R,6S)-6-<(2S,3R,4S,6R,7R,8R,9S,10S,11S)-2-methoxy-3,7,9,11-tetramethyl-8,10-dihydroxy-4,6-((R)-para-methoxybenzylidenedioxy)-13-((2S,4R,6S)-2-methyl-4-methoxytetrahydropyran-6-yl)-tridecan-1-yl>-5,6-dihydro-2H-pyran-2-yl>-7-tert-...

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Technology Process of (E,E,7S)-methyl-8-<(2R,6S)-6-<(2S,3R,4S,6R,7R,8R,9S,10S,11S)-2-methoxy-3,7,9,11-tetramethyl-8,10-dihydroxy-4,6-((R)-para-methoxybenzylidenedioxy)-13-((2S,4R,6S)-2-methyl-4-methoxytetrahydropyran-6-yl)-tridecan-1-yl>-5,6-dihydro-2H-pyran-2-yl>-7-tert-...

There total 1 articles about (E,E,7S)-methyl-8-<(2R,6S)-6-<(2S,3R,4S,6R,7R,8R,9S,10S,11S)-2-methoxy-3,7,9,11-tetramethyl-8,10-dihydroxy-4,6-((R)-para-methoxybenzylidenedioxy)-13-((2S,4R,6S)-2-methyl-4-methoxytetrahydropyran-6-yl)-tridecan-1-yl>-5,6-dihydro-2H-pyran-2-yl>-7-tert-... which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

(E,E,7S)-methyl-8-<(2R,6S)-6-<(2S,3R,4S,6R,7S,8S,9S,10S,11S)-8,10-di-tert-butylsilylenedioxy-2-methoxy-4,6-((R)-para-methoxybenzylidenedioxy)-13-((2S,4R,6S)-2-methyl-4-methoxytetrahydropyran-6-yl)-3,7,9,11-tetramethyltridecan-1-yl>-5,6-dihydro-2H-... (157117-37-8) → (E,E,7S)-methyl-8-<(2R,6S)-6-<(2S,3R,4S,6R,7R,8R,9S,10S,11S)-2-methoxy-3,7,9,11-tetramethyl-8,10-dihydroxy-4,6-((R)-para-methoxybenzylidenedioxy)-13-((2S,4R,6S)-2-methyl-4-methoxytetrahydropyran-6-yl)-tridecan-1-yl>-5,6-dihydro-2H-pyran-2-yl>-7-tert-... (158751-34-9)

Guidance literature:

With pyridine; pyridine hydrogenfluoride; In tetrahydrofuran; at 20 ℃; for 0.333333h;

DOI:10.1021/ja00099a091

Reference yield: 100.0%

(E,E,7S)-methyl-8-<(2R,6S)-6-<(2S,3R,4S,6R,7R,8R,9S,10S,11S)-2-methoxy-3,7,9,11-tetramethyl-8,10-dihydroxy-4,6-((R)-para-methoxybenzylidenedioxy)-13-((2S,4R,6S)-2-methyl-4-methoxytetrahydropyran-6-yl)-tridecan-1-yl>-5,6-dihydro-2H-pyran-2-yl>-7-tert-... (158751-34-9) → (E,E,7S)-8-<(2R,6S)-6-<(2S,3R,4S,6R,7R,8R,9S,10S,11S)-2-methoxy-3,7,9,11-tetramethyl-8,10-dihydroxy-4,6-((R)-para-methoxybenzylidenedioxy)-13-((2S,4R,6S)-2-methyl-4-methoxytetrahydropyran-6-yl)-tridecan-1-yl>-5,6-dihydro-2H-pyran-2-yl>-7-tert-butyldi... (158751-35-0)

Guidance literature:

With sodium hydroxide; In methanol; for 2h; Heating;

DOI:10.1016/0040-4020(95)00549-N

Reference yield:

(E,E,7S)-methyl-8-<(2R,6S)-6-<(2S,3R,4S,6R,7R,8R,9S,10S,11S)-2-methoxy-3,7,9,11-tetramethyl-8,10-dihydroxy-4,6-((R)-para-methoxybenzylidenedioxy)-13-((2S,4R,6S)-2-methyl-4-methoxytetrahydropyran-6-yl)-tridecan-1-yl>-5,6-dihydro-2H-pyran-2-yl>-7-tert-... (158751-34-9) → C53H86O11Si (158751-37-2)

Guidance literature:

Multi-step reaction with 3 steps

1: NaOMe / methanol; H₂O / 2 h / 60 °C

2: Et₃N / toluene / 2 h / 20 °C

3: DMAP / toluene / 60 °C

With dmap; sodium methylate; triethylamine; In methanol; water; toluene;

DOI:10.1021/ja00099a091

upstream raw materials:

(E,E,7S)-methyl-8-<(2R,6S)-6-<(2S,3R,4S,6R,7S,8S,9S,10S,11S)-8,10-di-tert-butylsilylenedioxy-2-methoxy-4,6-((R)-para-methoxybenzylidenedioxy)-13-((2S,4R,6S)-2-methyl-4-methoxytetrahydropyran-6-yl)-3,7,9,11-tetramethyltridecan-1-yl>-5,6-dihydro-2H-...

Downstream raw materials:

(E,E,7S)-8-<(2R,6S)-6-<(2S,3R,4S,6R,7R,8R,9S,10S,11S)-2-methoxy-3,7,9,11-tetramethyl-8,10-dihydroxy-4,6-((R)-para-methoxybenzylidenedioxy)-13-((2S,4R,6S)-2-methyl-4-methoxytetrahydropyran-6-yl)-tridecan-1-yl>-5,6-dihydro-2H-pyran-2-yl>-7-tert-butyldi...

C₅₃H₈₆O₁₁Si

C₅₃H₈₆O₁₁Si