chlorodiethylaminophenylphosphine(pentacarbonyl)tungsten⁽⁰⁾

Base Information

Chemical Name:chlorodiethylaminophenylphosphine(pentacarbonyl)tungsten⁽⁰⁾
CAS No.:126289-63-2
Molecular Formula:C₁₅H₁₅ClNO₅PW
Molecular Weight:539.565
Hs Code.:

chlorodiethylaminophenylphosphine(pentacarbonyl)tungsten<sup>(0)</sup>

Synonyms:chlorodiethylaminophenylphosphine(pentacarbonyl)tungsten⁽⁰⁾

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Chemical Property of chlorodiethylaminophenylphosphine(pentacarbonyl)tungsten⁽⁰⁾

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Technology Process of chlorodiethylaminophenylphosphine(pentacarbonyl)tungsten⁽⁰⁾

There total 1 articles about chlorodiethylaminophenylphosphine(pentacarbonyl)tungsten⁽⁰⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 93.0%

: 126306-20-5
bis(diethylamino)phenylphosphine(pentacarbonyl)tungsten⁽⁰⁾

: 126289-63-2
chlorodiethylaminophenylphosphine(pentacarbonyl)tungsten⁽⁰⁾

: 660-68-4
diethyl amine hydrochloride

Guidance literature:: With hydrogenchloride; In pentane; Under stirring a strong stream of hydrogenhalogenide is bubbled for 3-10 min through the cooled (-50-0°C) soln. of phosphine complex (inert atmosphere).; Solvent is evapd. at room temp. in vac., residue is digested with pentane, dialkylamminhydrohalogenide is filtered off, filtrate is dried to dryness in vac., recrystn. from pentane (-78°C), not purely isolated.;
DOI:10.1016/0022-328X(89)85002-8

Reference yield:

: 16853-85-3
lithium aluminium tetrahydride

: 126289-63-2
chlorodiethylaminophenylphosphine(pentacarbonyl)tungsten⁽⁰⁾

: 82839-12-1
diethylaminophenylphosphine-pentacarbonyl-tungsten⁽⁰⁾=Diethylaminophenylphosphin-pentacarbonyl-wolfram⁽⁰⁾

Guidance literature:: In diethyl ether; (Ar); dropwise addn. of W-compound to cooled suspension of LiAlH in ether under stirring at -80°C; warming to room temp. within 3 h; stirring for 6 h; filtn.; removal of solvent in vac. at room temp.; extn. with pentane; filtn.; removal of solvent in vac.; extn. with pentane; chromy. (silica gel/pentane); elem. anal.; IR; (31)P NMR; mass spectrum;
DOI:10.1016/0022-328X(90)85169-Y