[η5-cyclopentadienyl(bis(dimethylsilyl(η1-tert-butylamido)))](benzyl)titanium

Base Information

Chemical Name:[η5-cyclopentadienyl(bis(dimethylsilyl(η1-tert-butylamido)))](benzyl)titanium
CAS No.:361191-24-4
Molecular Formula:C₂₄H₄₀N₂Si₂Ti
Molecular Weight:460.646
Hs Code.:

Synonyms:[η5-cyclopentadienyl(bis(dimethylsilyl(η1-tert-butylamido)))](benzyl)titanium

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Chemical Property of [η5-cyclopentadienyl(bis(dimethylsilyl(η1-tert-butylamido)))](benzyl)titanium

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Technology Process of [η5-cyclopentadienyl(bis(dimethylsilyl(η1-tert-butylamido)))](benzyl)titanium

There total 2 articles about [η5-cyclopentadienyl(bis(dimethylsilyl(η1-tert-butylamido)))](benzyl)titanium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 17520-19-3
tetrabenzyl titanium

: 361191-24-4
[η5-cyclopentadienyl(bis(dimethylsilyl(η1-tert-butylamido)))](benzyl)titanium

Guidance literature:: In toluene; by syringe equimolar amt. of C5H4(SiMe2(NH(t)Bu))2 added to soln. of Ti(CH2Ph)4 cooled to 0°C; then yellow soln. under reflux warmed for 5 h to 65°C.; solvent removed under vac., residue extd. into pentane (70 mL); isolation by filtration and removal of solvent; elem.anal.; detd. by NMR;
DOI:10.1002/1521-3773(20010702)40:13<2495::AID-ANIE2495>3.0.CO;2-R

Reference yield: 98.0%

: C₅H₄(Si(CH₃)2(NHC(CH₃)3))2

: 17520-19-3
tetrabenzyl titanium

: 361191-24-4
[η5-cyclopentadienyl(bis(dimethylsilyl(η1-tert-butylamido)))](benzyl)titanium

Guidance literature:: In toluene; all manipulations under Ar atm.; soln. of Ti compd. cooled to 0°Cand Si compd. added by syringe, warmed at 70°C for 5 h; after stop of evolution of gas, solvent removed in vac., residue extd. with pentane, filtered, solvent removed, recrystd. from hexane, elem. anal.;
DOI:10.1002/ejic.200200698

Reference yield: 77.0%

: 361191-24-4
[η5-cyclopentadienyl(bis(dimethylsilyl(η1-tert-butylamido)))](benzyl)titanium

: 554-68-7
triethylamine hydrochloride

: 823809-58-1
chloro[η5-cyclopentadienyl(dimethylsilyl(tert-butylamino))(dimethylsilyl(η1-tert-butylamido))](benzyl)titanium

Guidance literature:: In toluene; byproducts: N(C2H5)3; (Ar), Ti complex in toluene added to suspn. of NEt3*HCl in toluene, stirred for 24 h at 70°C; evapd.(vac.), extd.(pentane), filtered, elem. anal.;
DOI:10.1002/ejic.200400083