(2S,3R,4S)-5-Benzyloxymethoxy-3-(tert-butyl-dimethyl-silanyloxy)-2,4-dimethyl-pentanal

Base Information

Chemical Name:(2S,3R,4S)-5-Benzyloxymethoxy-3-(tert-butyl-dimethyl-silanyloxy)-2,4-dimethyl-pentanal
CAS No.:86534-91-0
Molecular Formula:C₂₁H₃₆O₄Si
Molecular Weight:380.6
Hs Code.:

Synonyms:(2S,3R,4S)-5-Benzyloxymethoxy-3-(tert-butyl-dimethyl-silanyloxy)-2,4-dimethyl-pentanal

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (2S,3R,4S)-5-Benzyloxymethoxy-3-(tert-butyl-dimethyl-silanyloxy)-2,4-dimethyl-pentanal

Chemical Property:

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Technology Process of (2S,3R,4S)-5-Benzyloxymethoxy-3-(tert-butyl-dimethyl-silanyloxy)-2,4-dimethyl-pentanal

There total 7 articles about (2S,3R,4S)-5-Benzyloxymethoxy-3-(tert-butyl-dimethyl-silanyloxy)-2,4-dimethyl-pentanal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 86534-90-9
(2R,3S,4S)-5-Benzyloxymethoxy-3-(tert-butyl-dimethyl-silanyloxy)-2,4-dimethyl-pentan-1-ol

: 86534-91-0
(2S,3R,4S)-5-Benzyloxymethoxy-3-(tert-butyl-dimethyl-silanyloxy)-2,4-dimethyl-pentanal

Guidance literature:: With pyridinium chlorochromate; methyloxirane; In dichloromethane;
DOI:10.1016/S0040-4039(00)81643-3

Reference yield:

: 3587-60-8
Benzyloxymethyl chloride

: 86534-91-0
(2S,3R,4S)-5-Benzyloxymethoxy-3-(tert-butyl-dimethyl-silanyloxy)-2,4-dimethyl-pentanal

Guidance literature:: Multi-step reaction with 3 steps

1: (iC₃H₇)2NC₂H₅ / CH₂Cl₂

2: DIBAL / CH₂Cl₂ / -78 °C

3: 95 percent / PCC, propylene oxide / CH₂Cl₂

With diisobutylaluminium hydride; N-ethyl-N,N-diisopropylamine; pyridinium chlorochromate; methyloxirane; In dichloromethane;
DOI:10.1016/S0040-4039(00)81643-3

Reference yield:

: (2S,3R,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-5-hydroxy-2,4-dimethyl-pentanoic acid

: 86534-91-0
(2S,3R,4S)-5-Benzyloxymethoxy-3-(tert-butyl-dimethyl-silanyloxy)-2,4-dimethyl-pentanal

Guidance literature:: Multi-step reaction with 4 steps

1: diethyl ether

2: (iC₃H₇)2NC₂H₅ / CH₂Cl₂

3: DIBAL / CH₂Cl₂ / -78 °C

4: 95 percent / PCC, propylene oxide / CH₂Cl₂

With diisobutylaluminium hydride; N-ethyl-N,N-diisopropylamine; pyridinium chlorochromate; methyloxirane; In diethyl ether; dichloromethane;
DOI:10.1016/S0040-4039(00)81643-3