86534-90-9

Upstream product

• 3587-60-8 Benzyloxymethyl chloride 
• 82281-55-8 (3S,4R,5S)-4-(tert-Butyl-dimethyl-silanyloxy)-3,5-dimethyl-1-trimethylsilanyloxy-cyclopentene 
• 86534-88-5 (2S,3R,4S)-3-(tert-Butyl-dimethyl-silanyloxy)-5-hydroxy-2,4-dimethyl-pentanoic acid methyl ester 
• 86534-89-6 (2S,3R,4S)-5-Benzyloxymethoxy-3-(tert-butyl-dimethyl-silanyloxy)-2,4-dimethyl-pentanoic acid methyl ester 

Downstream Products

• 86534-91-0 (2S,3R,4S)-5-Benzyloxymethoxy-3-(tert-butyl-dimethyl-silanyloxy)-2,4-dimethyl-pentanal 
• 160691-37-2 (2S,3R,4S,5R,6R)-3,5-(isopropylidenedioxy)-2,4,6-trimethyl-7-(phenylthio)heptan-1-ol 
• 86534-98-7 (SRS,2S,3R,4S,5R,6R)-3,5-(isopropylidenedioxy)-2,4,6-trimethyl-7-(phenylsulfinyl)heptan-1-ol 
• 86534-94-3 (4R,5S,6R)-4-((S)-2-Benzyloxymethoxy-1-methyl-ethyl)-6-isopropenyl-2,2,5-trimethyl-[1,3]dioxane 
• 86534-97-6 (2S,3S,4S,5R,6S)-7-hydroxy-3,5-(isopropylidenedioxy)-2,4,6-trimethylheptyl p-toluenesulfonate 
• 86534-99-8 (4R,5S,6R)-4-((R)-2-Benzenesulfinyl-1-methyl-ethyl)-6-((S)-2-benzyloxymethoxy-1-methyl-ethyl)-2,2,5-trimethyl-[1,3]dioxane 
• 86534-96-5 Toluene-4-sulfonic acid (S)-2-[(4S,5S,6R)-6-((S)-2-benzyloxymethoxy-1-methyl-ethyl)-2,2,5-trimethyl-[1,3]dioxan-4-yl]-propyl ester 
• 86535-02-6 (2R,3R,4R,5R,6S)-5-(tert-Butyl-dimethyl-silanyloxy)-7-hydroxy-3-(2-methoxy-ethoxymethoxy)-2,4,6-trimethyl-heptanoic acid 2,6-dimethyl-phenyl ester 
• 86535-03-7 (2R,3R,4R,5S)-5-(tert-Butyl-dimethyl-silanyloxy)-3-(2-methoxy-ethoxymethoxy)-2,4,6-trimethyl-hept-6-enoic acid 2,6-dimethyl-phenyl ester 
• 86535-00-4 (2R,3R,4R,5R,6S)-7-Benzyloxymethoxy-5-(tert-butyl-dimethyl-silanyloxy)-3-(2-methoxy-ethoxymethoxy)-2,4,6-trimethyl-heptanoic acid 2,6-dimethyl-phenyl ester 
• 86534-95-4 (2S,3S,4R,5R,6S)-7-Benzyloxymethoxy-2,4,6-trimethyl-heptane-1,3,5-triol 
• 86534-93-2 (2S,3S,4R,5R,6S)-7-Benzyloxymethoxy-5-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-2,4,6-trimethyl-heptanoic acid 2,6-dimethyl-phenyl ester 
• 86534-93-2 (2R,3R,4R,5R,6S)-7-Benzyloxymethoxy-5-(tert-butyl-dimethyl-silanyloxy)-3-hydroxy-2,4,6-trimethyl-heptanoic acid 2,6-dimethyl-phenyl ester 

Relevant academic research and scientific papers

STUDIES IN MACROLIDE SYNTHESIS: A SYNTHESIS OF TWO CHIRAL FRAGMENTS OF OLEANDOMYCIN AND LANKAMYCIN

A synthesis of the two structurally-related chiral fragments, C1-C7 and C8-C13, of oleandomycin and lankamycin is described.