9-(4-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl)-9H-3,9'-bicarbazole

Base Information

• Chemical Name: 9-(4-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl)-9H-3,9'-bicarbazole
• CAS No.: 1480889-49-3
• Molecular Formula: C₄₅H₂₉N₅
• Molecular Weight: 639.759
• Mol file: 1480889-49-3.mol

Synonyms:9-(4-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl)-9H-3,9'-bicarbazole

Chemical Property of 9-(4-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl)-9H-3,9'-bicarbazole

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 9-(4-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl)-9H-3,9'-bicarbazole

There total 3 articles about 9-(4-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl)-9H-3,9'-bicarbazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

2-di(4-fluorophenyl)-4,6-diphenyl-1,3,5-triazine (203450-08-2) + 9-(9H-carbazol-3-yl)-9H-carbazole (18628-07-4) → 9-(4-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl)-9H-3,9'-bicarbazole (1480889-49-3)

Guidance literature:

With caesium carbonate; In N,N-dimethyl-formamide; at 160 ℃; for 12h;

DOI:10.1039/c9tc05550a

Reference yield: 71.3%

9-(9H-carbazol-3-yl)-9H-carbazole (18628-07-4) + 2-(4-bromobenzenyl)-4,6-diphenyl-1,3,5-triazine (23449-08-3) → 9-(4-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl)-9H-3,9'-bicarbazole (1480889-49-3)

Guidance literature:

With tri-tert-butyl phosphine; potassium tert-butylate; palladium diacetate; In 1,4-dioxane; water; toluene; for 6h; Reflux;

DOI:10.1039/d1tc03307g

Reference yield:

2-chloro-4,6-diphenyl-1,3,5-triazine (3842-55-5) + 4-fluoroboronic acid (1765-93-1) → 9-(4-(4,6-diphenyl-1,3,5-triazin-2-yl)phenyl)-9H-3,9'-bicarbazole (1480889-49-3)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate / tetrahydrofuran / 4 h / Inert atmosphere; Reflux

2: caesium carbonate / N,N-dimethyl-formamide / 12 h / 160 °C

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; caesium carbonate; In tetrahydrofuran; N,N-dimethyl-formamide;

DOI:10.1039/c9tc05550a

upstream raw materials:

2-chloro-4,6-diphenyl-1,3,5-triazine

4-fluoroboronic acid

2-di(4-fluorophenyl)-4,6-diphenyl-1,3,5-triazine

9-(9H-carbazol-3-yl)-9H-carbazole