[1-phenyl-2-(2-pyridyl)-5-(2-thienyl)phosphole]PtCl₂

Base Information

• Chemical Name: [1-phenyl-2-(2-pyridyl)-5-(2-thienyl)phosphole]PtCl₂
• CAS No.: 825651-71-6
• Molecular Formula: C₂₃H₂₀Cl₂NPPtS
• Molecular Weight: 639.444
• Mol file: 825651-71-6.mol

Synonyms:[1-phenyl-2-(2-pyridyl)-5-(2-thienyl)phosphole]PtCl₂

Chemical Property of [1-phenyl-2-(2-pyridyl)-5-(2-thienyl)phosphole]PtCl₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [1-phenyl-2-(2-pyridyl)-5-(2-thienyl)phosphole]PtCl₂

There total 2 articles about [1-phenyl-2-(2-pyridyl)-5-(2-thienyl)phosphole]PtCl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

bis(benzonitrile)dichloroplatinum(II) (14873-63-3,15617-19-3,51921-56-3) + 1-phenyl-2-(2-pyridyl)-5-(2-thienyl)phosphole → [1-phenyl-2-(2-pyridyl)-5-(2-thienyl)phosphole]PtCl2 (825651-71-6)

Guidance literature:

In dichloromethane; at 20 ℃; for 1h;

Reference yield: 79.0%

bis(acetonitrile)dichloroplatinum(II) (13869-38-0,21264-32-4,13869-42-6) + 1-phenyl-2-(2-pyridyl)-5-(2-thienyl)phosphole → [1-phenyl-2-(2-pyridyl)-5-(2-thienyl)phosphole]PtCl2 (825651-71-6)

Guidance literature:

In dichloromethane; under Ar atm. soln. phosphole in CH2Cl2 was added at room temp. to soln.PtCl2(MeCN)2 in CH2Cl2 and stirred at room temp. for 1 h; volatiles were removed in vacuo, residue was washed with Et2O and dried in vacuo; elem. anal.;

DOI:10.1021/om049510i

Reference yield: 83.0%

[1-phenyl-2-(2-pyridyl)-5-(2-thienyl)phosphole]PtCl2 (825651-71-6) → [1-phenyl-2-(2-pyridyl)-5-(2-thienyl)phosphol-2-ene]PtCl2

Guidance literature:

With pyridine; In dichloromethane; under Ar atm. soln. Pd complex and pyridine in CH2Cl2 was heated at 45°C for 3 days; solvent was removed, residue was washed with Et2O and dried in vacuo; elem. anal.;

DOI:10.1021/om049510i

upstream raw materials:

bis(benzonitrile)dichloroplatinum(II)

bis(acetonitrile)dichloroplatinum(II)