Bis(benzonitrile)dichloroplatinum

Base Information

• Chemical Name: Bis(benzonitrile)dichloroplatinum
• CAS No.: 14873-63-3
• Molecular Formula: C14H10Cl2N2Pt
• Molecular Weight: 472.233
• European Community (EC) Number: 238-943-7
• Mol file: 14873-63-3.mol

Synonyms:14873-63-3;Bis(benzonitrile)dichloroplatinum(II);Dichlorobis(benzonitrile)platinum(II);Bis(benzonitrile)dichloroplatinum;benzonitrile;dichloroplatinum;cis-Bis(benzonitrile)dichloroplatinum(II);15617-19-3;EINECS 238-943-7;C12H10Cl2N2Pt;C12-H10-Cl2-N2-Pt;Platinum, bis(benzonitrile)dichloro-, cis-;C14H10Cl2N2Pt;Platinum, bis(benzonitrile)dichloro-, (SP-4-2)-;Platinum, bis(benzonitrile)dichloro-;MFCD00013125;PtCl2(PhCN)2;SCHEMBL288445;C14-H10-Cl2-N2-Pt;AKOS015888404;SC10696;FT-0624707;E81057;cis-Bis(benzonitrile)dichloroplatinum(II), 98%;BIS(BENZONITRILE)DICHLOROPLATINATE (II);BIS(BENZONITRILE)DICHLOROPLATINUM(II);CIS-BIS(BENZONITRILE)DICHLOROPLATINUM(II);DICHLOROBIS(BENZONITRILE)PLATINUM(II)

Chemical Property of Bis(benzonitrile)dichloroplatinum

Chemical Property:

• Vapor Pressure: 0.524mmHg at 25°C
• Melting Point: 224 °C (dec.)(lit.)
• Boiling Point: 191.1 °C at 760 mmHg
• Flash Point: 71.7 °C
• PSA: 47.58000
• LogP: -2.87794
• Storage Temp.: Keep in dark place,Inert atmosphere,Room temperature
• Solubility.: Slightly soluble in acetone, chloroform
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 470.986898
• Heavy Atom Count: 19
• Complexity: 106

Purity/Quality:

97% ^*data from raw suppliers

Dichlorobis(benzonitrile)platinum(II), 99% ^*data from reagent suppliers

Safty Information:

• Statements: 20/21/22
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C#N.C1=CC=C(C=C1)C#N.Cl[Pt]Cl
• Uses: Bis(benzonitrile)dichloroplatinum(II) is used as a catalyst for asymmetric hydroformylation reactions, allylation reactions, cyclopropanation reactions, hydrosilylation reactions and carbene insertion into O-H bonds of alcohols.

Technology Process of Bis(benzonitrile)dichloroplatinum

There total 18 articles about Bis(benzonitrile)dichloroplatinum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

tetramethylammonium tetrachloroplatinate(II) + benzonitrile (100-47-0) → cis-bis(benzonitrile)dichloroplatinum(II) (14873-63-3)

Guidance literature:

In not given; excess nitrile;

DOI:10.1139/v96-018

Reference yield: 95.2%

benzonitrile (100-47-0) + platinum(II) chloride (10025-65-7) → bis(benzonitrile)dichloroplatinum(II) (14873-63-3,15617-19-3,51921-56-3)

Guidance literature:

In benzonitrile; inert atmosphere; 100°C, 20 min; hot filtration (Celite), pptn. on addn. of hexanes, collection (filtration), washing (hexanes);

DOI:10.1016/s0020-1693(97)05642-9

Reference yield: 88.0%

benzonitrile (100-47-0) + platinum(II) chloride (10025-65-7) → trans-bis(benzonitrile)dichloroplatinum(II) (14873-63-3,15617-19-3,51921-56-3)

Guidance literature:

In benzonitrile; suspn. of Pt compd. in benzonitrile was stirred at 100°C for 3 h; cooled to room temp.; petroleum ether added; filtered; washed (petrol ether); extd. (CH2Cl2); filtered; evapd.; chromd. (SiO2, CH2Cl2);

DOI:10.1039/b807410k

upstream raw materials:

bis(acetonitrile)dichloroplatinum(II)

benzonitrile

platinum(II) chloride

tetrachloroplatinum(II)

Downstream raw materials:

[1-phenyl-2,5-di(2-pyridyl)phosphole]PtCl₂

[1-phenyl-2-(2-pyridyl)-5-(2-thienyl)phosphole]PtCl₂

((C₂H₅)4N)⁽¹⁺⁾*(Pt(C₆H₅CN)Cl₃)^(1-)=((C₂H₅)4N)(Pt(C₆H₅CN)Cl₃)

trans-dichlorobis(triphenylphosphine)platinum(II)