(2E,4E,8E,6R,7S)-1-acetoxy-7-[6-deoxy-4-O-methyl-2,3-O-(1,1,4,4,-tetraphenyldisilabutandi-1,4-yl)-α-L-glucopyranosyl]-9-iodo-2,4,6-trimethyl-2,4,8-nonatriene

Base Information

Chemical Name:(2E,4E,8E,6R,7S)-1-acetoxy-7-[6-deoxy-4-O-methyl-2,3-O-(1,1,4,4,-tetraphenyldisilabutandi-1,4-yl)-α-L-glucopyranosyl]-9-iodo-2,4,6-trimethyl-2,4,8-nonatriene
CAS No.:795290-02-7
Molecular Formula:C₄₇H₅₅IO₇Si₂
Molecular Weight:915.025
Hs Code.:

(2E,4E,8E,6R,7S)-1-acetoxy-7-[6-deoxy-4-O-methyl-2,3-O-(1,1,4,4,-tetraphenyldisilabutandi-1,4-yl)-α-L-glucopyranosyl]-9-iodo-2,4,6-trimethyl-2,4,8-nonatriene

Synonyms:(2E,4E,8E,6R,7S)-1-acetoxy-7-[6-deoxy-4-O-methyl-2,3-O-(1,1,4,4,-tetraphenyldisilabutandi-1,4-yl)-α-L-glucopyranosyl]-9-iodo-2,4,6-trimethyl-2,4,8-nonatriene

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Chemical Property of (2E,4E,8E,6R,7S)-1-acetoxy-7-[6-deoxy-4-O-methyl-2,3-O-(1,1,4,4,-tetraphenyldisilabutandi-1,4-yl)-α-L-glucopyranosyl]-9-iodo-2,4,6-trimethyl-2,4,8-nonatriene

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Technology Process of (2E,4E,8E,6R,7S)-1-acetoxy-7-[6-deoxy-4-O-methyl-2,3-O-(1,1,4,4,-tetraphenyldisilabutandi-1,4-yl)-α-L-glucopyranosyl]-9-iodo-2,4,6-trimethyl-2,4,8-nonatriene

There total 14 articles about (2E,4E,8E,6R,7S)-1-acetoxy-7-[6-deoxy-4-O-methyl-2,3-O-(1,1,4,4,-tetraphenyldisilabutandi-1,4-yl)-α-L-glucopyranosyl]-9-iodo-2,4,6-trimethyl-2,4,8-nonatriene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: Acetic acid (2E,4E,8E)-(6R,7S)-7-(tert-butyl-dimethyl-silanyloxy)-9-iodo-2,4,6-trimethyl-nona-2,4,8-trienyl ester

: 795290-02-7
(2E,4E,8E,6R,7S)-1-acetoxy-7-[6-deoxy-4-O-methyl-2,3-O-(1,1,4,4,-tetraphenyldisilabutandi-1,4-yl)-α-L-glucopyranosyl]-9-iodo-2,4,6-trimethyl-2,4,8-nonatriene

Guidance literature:: Multi-step reaction with 2 steps

1.1: 393 mg / TBAF / tetrahydrofuran / 2 h / 20 °C

2.1: 2,6-tert-butyl-4-methyl pyridine / toluene; diethyl ether / 1 h / 20 °C

2.2: Tf₂O / diethyl ether; toluene / 2 h / -80 - -35 °C

With 2,6-di-tert-butyl-4-methylpyridine; tetrabutyl ammonium fluoride; In tetrahydrofuran; diethyl ether; toluene;
DOI:10.1002/chem.200600462

Reference yield:

: 795289-98-4
phenyl 6-deoxy-4-O-methyl-1-thio-α-L-rhamnopyranoside

: 795290-02-7
(2E,4E,8E,6R,7S)-1-acetoxy-7-[6-deoxy-4-O-methyl-2,3-O-(1,1,4,4,-tetraphenyldisilabutandi-1,4-yl)-α-L-glucopyranosyl]-9-iodo-2,4,6-trimethyl-2,4,8-nonatriene

Guidance literature:: Multi-step reaction with 3 steps

1.1: 92 percent / imidazole / dimethylformamide / 1 h / 0 °C

2.1: 92 percent / mCPBA / CH₂Cl₂ / 2 h / -78 - -20 °C

3.1: 2,6-tert-butyl-4-methyl pyridine / toluene; diethyl ether / 1 h / 20 °C

3.2: Tf₂O / diethyl ether; toluene / 2 h / -80 - -35 °C

With 1H-imidazole; 2,6-di-tert-butyl-4-methylpyridine; 3-chloro-benzenecarboperoxoic acid; In diethyl ether; dichloromethane; N,N-dimethyl-formamide; toluene;
DOI:10.1002/chem.200600462

Reference yield:

: 795289-99-5
phenyl 6-deoxy-4-O-methyl-2,3-O-(1,1,4,4-tetraphenyldisilabutandi-1,4-yl)-1-thio-α-L-glucopyranoside

: 795290-02-7
(2E,4E,8E,6R,7S)-1-acetoxy-7-[6-deoxy-4-O-methyl-2,3-O-(1,1,4,4,-tetraphenyldisilabutandi-1,4-yl)-α-L-glucopyranosyl]-9-iodo-2,4,6-trimethyl-2,4,8-nonatriene

Guidance literature:: Multi-step reaction with 2 steps

1.1: 92 percent / mCPBA / CH₂Cl₂ / 2 h / -78 - -20 °C

2.1: 2,6-tert-butyl-4-methyl pyridine / toluene; diethyl ether / 1 h / 20 °C

2.2: Tf₂O / diethyl ether; toluene / 2 h / -80 - -35 °C

With 2,6-di-tert-butyl-4-methylpyridine; 3-chloro-benzenecarboperoxoic acid; In diethyl ether; dichloromethane; toluene;
DOI:10.1002/chem.200600462