1-[6-phenyl-3-(2-pyridyl)-1,2,4-triazin-5-yl]-2-phenyl-1,2-dicarba-closo-dodecaborane

Base Information

Chemical Name:1-[6-phenyl-3-(2-pyridyl)-1,2,4-triazin-5-yl]-2-phenyl-1,2-dicarba-closo-dodecaborane
CAS No.:680572-25-2
Molecular Formula:C₂₂H₂₄B₁₀N₄
Molecular Weight:452.569
Hs Code.:

Synonyms:1-[6-phenyl-3-(2-pyridyl)-1,2,4-triazin-5-yl]-2-phenyl-1,2-dicarba-closo-dodecaborane

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Chemical Property of 1-[6-phenyl-3-(2-pyridyl)-1,2,4-triazin-5-yl]-2-phenyl-1,2-dicarba-closo-dodecaborane

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Technology Process of 1-[6-phenyl-3-(2-pyridyl)-1,2,4-triazin-5-yl]-2-phenyl-1,2-dicarba-closo-dodecaborane

There total 2 articles about 1-[6-phenyl-3-(2-pyridyl)-1,2,4-triazin-5-yl]-2-phenyl-1,2-dicarba-closo-dodecaborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 16390-61-7
1-phenyl-1,2-closo-C₂B₁₀H₁₁

: 453556-95-1
6-phenyl-3-(2'-pyridyl)-1,2,4-triazine-4-oxide

: 680572-25-2
1-[6-phenyl-3-(2-pyridyl)-1,2,4-triazin-5-yl]-2-phenyl-1,2-dicarba-closo-dodecaborane

Guidance literature:: With t-BuLi; Me₂NCOCl; In tetrahydrofuran; pentane; (Ar); std. Schlenk technique; soln. of BuLi in pentane was added to soln. of carborane in THF at room temp.; soln. was added dropwise to suspn. of N-oxide in THF at -50°C; mixt. was stirred for 20 min; Me2NCOCl was added; solvent removed; residue treated with toluene; soln. septd.; solvent removed; residue treated with MeCN; filtered; recrystd. (MeCN); elem. anal.;
DOI:10.1021/om051058v

Reference yield: 47.0%

: 16390-61-7
1-phenyl-1,2-closo-C₂B₁₀H₁₁

: 453556-96-2
6-phenyl-3-(pyridin-2-yl)-1,2,4-triazine-5-carbonitrile

: 680572-25-2
1-[6-phenyl-3-(2-pyridyl)-1,2,4-triazin-5-yl]-2-phenyl-1,2-dicarba-closo-dodecaborane

Guidance literature:: With t-BuLi; In tetrahydrofuran; pentane; (Ar); std. Schlenk technique; soln. of BuLi in pentane was added to soln. of carborane in THF at room temp.; soln. was added dropwise to soln. of triazine in THF at -50°C; mixt. was stirred for 25 min; acetic acid added; solvent removed; residue treated with toluene; soln. septd.; solvent removed; residue treated with MeCN; filtered; recrystd. (MeCN);
DOI:10.1021/om051058v

Reference yield: 90.0%

: 680572-25-2
1-[6-phenyl-3-(2-pyridyl)-1,2,4-triazin-5-yl]-2-phenyl-1,2-dicarba-closo-dodecaborane

: 121-46-0
bicyclo[2.2.1]hepta-2,5-diene

: 896741-93-8
1-(5-phenyl-2,2'-bipyridin-6-yl)-2-phenyl-1,2-dicarba-closo-dodecaborane

Guidance literature:: In toluene; (Ar); std. Schlenk technique; soln. of carborane and norbornadiene in toluene was refluxed for 5 h; solvent removed (vac.); residue treated with MeCN; filtered; elem. anal.;
DOI:10.1021/om051058v