Benzene, 1,1'-[(phenylmethylene)bis(oxy)]bis-

Base Information

• Chemical Name: Benzene, 1,1'-[(phenylmethylene)bis(oxy)]bis-
• CAS No.: 35822-60-7
• Molecular Formula: C₁₉H₁₆O₂
• Molecular Weight: 276.335
• DSSTox Substance ID: DTXSID601251644
• Nikkaji Number: J3.326.937D
• Mol file: 35822-60-7.mol

Synonyms:SCHEMBL7564026;DTXSID601251644;35822-60-7;Benzene, 1,1'-[(phenylmethylene)bis(oxy)]bis-

Chemical Property of Benzene, 1,1'-[(phenylmethylene)bis(oxy)]bis-

Chemical Property:

• XLogP3: 5.2
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 276.115029749
• Heavy Atom Count: 21
• Complexity: 253

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C(OC2=CC=CC=C2)OC3=CC=CC=C3

Technology Process of Benzene, 1,1'-[(phenylmethylene)bis(oxy)]bis-

There total 1 articles about Benzene, 1,1'-[(phenylmethylene)bis(oxy)]bis- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

benzylidene dichloride (98-87-3) + phenol (108-95-2,27073-41-2) → (phenylmethylene)bis(oxy)dibenzene (35822-60-7)

Guidance literature:

With sodium hydroxide; In dimethyl sulfoxide; at 70 ℃; for 3h;

DOI:10.1002/chem.201403285

Reference yield: 88.0%

(phenylmethylene)bis(oxy)dibenzene (35822-60-7) + isopropenylbenzene (98-83-9,6144-04-3,25014-31-7,42612-14-6) → 4-methyl-2,4-diphenylchroman

Guidance literature:

With [Au(2,6-bis(diisopropylphenyl)imidazol-2-ylidene)]SbF₆; In dichloromethane; at -20 ℃; diastereoselective reaction; Inert atmosphere;

DOI:10.1002/chem.201403285

Reference yield: 87.0%

(E)-buta-1,3-dienylbenzene (16939-57-4) + (phenylmethylene)bis(oxy)dibenzene (35822-60-7) → 2-phenyl-4-[(E)-styryl]chroman

Guidance literature:

With [Au(2,6-bis(diisopropylphenyl)imidazol-2-ylidene)]SbF₆; In dichloromethane; at -20 ℃; diastereoselective reaction; Inert atmosphere;

DOI:10.1002/chem.201403285

upstream raw materials:

benzylidene dichloride

phenol

Downstream raw materials:

2,4-diphenylchroman

cis-2,4-diphenylchroman

4-(4-methoxyphenyl)-2-phenylchroman

flavan-4β-phenyl sulphide